Showing all your work, calculate the mol% of Pd used in this reaction where R and R’ = H.   aryl halide mw: 185.02 g/mol phenyl boronic acid: 121.93 g/mol  Pd acetate: 224.5 g/mol

Fundamentals Of Analytical Chemistry
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ISBN:9781285640686
Author:Skoog
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Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.9QAP
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A common way to determine the catalyst: limiting reactant ratio in a catalytic reaction is to report the amount of catalyst used in mol%. For example, 5 mol% catalyst means that the reaction uses 5% as much catalyst as the limiting reactant. Showing all your work, calculate the mol% of Pd used in this reaction where R and R’ = H.

 

aryl halide mw: 185.02 g/mol

phenyl boronic acid: 121.93 g/mol 

Pd acetate: 224.5 g/mol 

 

.5g
.35g
R
R
B(OH)2
2.0 mg
Pd(OAc)2, PPH3
+
aq Na2CO3
Br
R'
n-PrOH
R = H, CH3
R' = H, CH3, OCH3
R'
Transcribed Image Text:.5g .35g R R B(OH)2 2.0 mg Pd(OAc)2, PPH3 + aq Na2CO3 Br R' n-PrOH R = H, CH3 R' = H, CH3, OCH3 R'
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