Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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**Select the expected major product(s) from the treatment of 1-pentyne with 1 equivalent of HBr in the presence of peroxides.**

Options:
- **A:** 2-bromo-1-pentene
- **B:** (E)-1-bromo-1-pentene
- **C:** (Z)-1-bromo-1-pentene
- **D:** A and B
- **E:** B and C

The selected answer is **B:** (E)-1-bromo-1-pentene. 

In an educational context, the treatment of alkynes with HBr in the presence of peroxides leads to anti-Markovnikov addition, favoring the formation of alkenes with bromine at the less substituted carbon. The presence of peroxides causes this reaction to proceed via a radical mechanism.
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Transcribed Image Text:**Select the expected major product(s) from the treatment of 1-pentyne with 1 equivalent of HBr in the presence of peroxides.** Options: - **A:** 2-bromo-1-pentene - **B:** (E)-1-bromo-1-pentene - **C:** (Z)-1-bromo-1-pentene - **D:** A and B - **E:** B and C The selected answer is **B:** (E)-1-bromo-1-pentene. In an educational context, the treatment of alkynes with HBr in the presence of peroxides leads to anti-Markovnikov addition, favoring the formation of alkenes with bromine at the less substituted carbon. The presence of peroxides causes this reaction to proceed via a radical mechanism.
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