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Select correct and most relevant mechanism for each of the following reaction. Hint: Review Chapter 11.4. Mechanism A: nucleophilic attack proton transfer CH₂ 5 Jy g H proton Br dilute H-Br: transfer = Mechanism B: dilute HBr Mechanism C: proton transfer nucleophilic attack H CH3 H CH3 Br 5-8-8-8 z z :Br = dilute H-Br: dilute H-Br: OA O Mechanism D: B nucleophilic attack dilute H-Br: = Br secondary carbocation proton disassosiation CH₂ primary carbanion Br: H.O HCH₂ tertiary carbocation hydrogen migration (rearrangement) proton disassosiation dilute H-Br: proton transfer H-Br: ** elimination H H. Br: CH₂ H H-Br: + tertiary carbocation proton transfer CH₂ elimination H-Br: proton transfer, Br nucleophilic attack Br-H secondary carbanion proton transfer Br dilute H-Br: Bri nucleophilic attack = H H H H₂ CH3 .Br Br CH3 tertiary carbocation

Select correct and most relevant mechanism for each of the following reaction. Hint: Review Chapter 11.4. Mechanism A: nucleophilic attack proton transfer CH₂ 5 Jy g H proton Br dilute H-Br: transfer = Mechanism B: dilute HBr Mechanism C: proton transfer nucleophilic attack H CH3 H CH3 Br 5-8-8-8 z z :Br = dilute H-Br: dilute H-Br: OA O Mechanism D: B nucleophilic attack dilute H-Br: = Br secondary carbocation proton disassosiation CH₂ primary carbanion Br: H.O HCH₂ tertiary carbocation hydrogen migration (rearrangement) proton disassosiation dilute H-Br: proton transfer H-Br: ** elimination H H. Br: CH₂ H H-Br: + tertiary carbocation proton transfer CH₂ elimination H-Br: proton transfer, Br nucleophilic attack Br-H secondary carbanion proton transfer Br dilute H-Br: Bri nucleophilic attack = H H H H₂ CH3 .Br Br CH3 tertiary carbocation

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Select correct and most relevant mechanism for each of the following reaction. Hint: Review Chapter 11.4. Mechanism A: nucleophilic attack proton transfer H.O HCH₂ 6-8=8²²²6 tertiary carbocation hydrogen migration (rearrangement) H CH3 H Mechanism B: dilute HBr Mechanism C: dilute H-Br: OA O O Mechanism D: B dilute H-Br: C D dilute H-Br: = CH₂ nucleophilic attack Br H proton proton transfer transfer secondary carbocation proton disassosiation CH₂ primary carbanion Br = dilute H-Br: proton disassosiation proton transfer H-Br: elimination H. Br: CH₂ H H CH3 H-Br: + tertiary carbocation proton transfer Br dilute H-Br: nucleophilic attack :Br CH₂ elimination H-Br: proton transfer, Br Br Br-H secondary carbanion proton transfer nucleophilic attack dilute H-Br: Bri nucleophilic attack = Br Br H H CH3 H H₂ CH3 .Br tertiary carbocation
Transcribed Image Text:Select correct and most relevant mechanism for each of the following reaction. Hint: Review Chapter 11.4. Mechanism A: nucleophilic attack proton transfer H.O HCH₂ 6-8=8²²²6 tertiary carbocation hydrogen migration (rearrangement) H CH3 H Mechanism B: dilute HBr Mechanism C: dilute H-Br: OA O O Mechanism D: B dilute H-Br: C D dilute H-Br: = CH₂ nucleophilic attack Br H proton proton transfer transfer secondary carbocation proton disassosiation CH₂ primary carbanion Br = dilute H-Br: proton disassosiation proton transfer H-Br: elimination H. Br: CH₂ H H CH3 H-Br: + tertiary carbocation proton transfer Br dilute H-Br: nucleophilic attack :Br CH₂ elimination H-Br: proton transfer, Br Br Br-H secondary carbanion proton transfer nucleophilic attack dilute H-Br: Bri nucleophilic attack = Br Br H H CH3 H H₂ CH3 .Br tertiary carbocation
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