Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Consider a galvanic electrochemical cell constructed using Cr/Cr* and Zn/Zn2* at 25 °C. The following half-reactions are provided for each metal: Crs* (aq) + 3 e Cr(s) E°red = -0.744 V Zn2*(aq) + 2 e Zn(s) E°red = -0.763 V What is the standard cell potential for this cell?arrow_forward== A certain half-reaction has a standard reduction potential E red - 1.32 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 1.00 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be…arrow_forwardConsider a galvanic electrochemical cell constructed using Cr/Cr** and Zn/Zn2* at 25 °C. The following half-reactions are provided for each metal: 3+ Cr**(aq) + 3 e → Cr(s) E°red = -0.744 V Zn2*(aq) + 2 e → Zn(s) E°red = -0.763 V What is the cell potential for this cell at 25 °C when [Zn2*] = 0.0323 M and [Cr3] = 0.1736 M?arrow_forward
- Given the following standard reduction potentials, E°red, which species has the greatest tendency to be oxidized? S (s) + 2 H+ + 2e− → H2S (g) E°red = +0.144 V O2 (g) + 4 H+ + 4e− → 2 H2O (l) E°red = +1.229 V Sn2+ (aq) + 2e− → Sn (s) E°red = −0.137 V HERE ARE THE OPTIONS: O2 (g) S (s) Sn (s) H2S (g)arrow_forwardGiven the standard reduction potentials, which combination in the answer choices below would produce the lowest cell voltage when combined into a voltaic cell? Remember that one of the half reactions will serve as the oxidation reaction. Use the equation: Ecell Ered (cathode) - Ered (anode) to calculate the cell voltage. = 12(s) + 2e → 21¯(aq) Ag+ (aq) + e- → Ag(s) Cu²+ (aq) + 2e-→ Cu(s) Cr³+(aq) +3e- → Cr(s) Al³+ (aq) + 3e- → Al(s) Sn²+ (aq) + 2 e- → Sn(s) 12(S) & Cr(s) Cu²+ (aq) & Sn(s) Cu²+ (aq) & Cr(s) Ag+ (aq) & Al(s) Ereduction 0.54 V 0.80 V 0.34 V - 0.74 V -1.66 V -0.14 Varrow_forwardRefer to the galvanic cell below (the contents of each half-cell are written beneath each compartment): Pt Cr 1.0 M MnO4 1.0 M Cr3+ 1.0 M Mn2+ 1.0 M Cr20,2- 1.0 M H* 1.0 M H* The standard reduction potentials are as follows: MnO,- + 8H+ + 5e- Cr,0-2- + 14H+ + 6e- → 2Cr3+ + 7H,0, E° = 1.33 V Mn2+ + 4H,0, E° = 1.51 V When current is allowed to flow, which species is reduced? Select one: O a. MnO4 O b. Cr3+ О с. H* O d. Cr20,2- е. Mn2+arrow_forward
- Calculate the standard cell potential, E, for the equation Cr(s) + F,(g) → Cr**(aq) + 2F (aq) Use the table of standard reduction potentials. E• cell %3D Varrow_forwardA certain half-reaction has a standard reduction potential Eed=+0.45 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 1.40 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell. olo Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? yes, there is a minimum. E red Ov Ar If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. no minimum Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? E = Ov yes, there is a maximum. red If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. no maximumarrow_forwardUse the standard reduction potentials given below to predict if a reaction will occur between Zn(s) and Cl2(g), when the two are brought in contact via standard half-cells in a voltaic cell. | Cl2(g) + 2e¯¯ →2C1¯¯ (aq) E Zn2+ = 1.360 V red (aq) + 2e → Zn(s) E = = -0.763 V red If a reaction will occur, write a balanced net ionic equation for the reaction, assuming that the product ions are in aqueous solution. If no reaction will occur, leave all boxes blank. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) + +arrow_forward
- Refer to the galvanic cell below (the contents of each half-cell are written beneath each compartment): V Pt 0.10 M MnO4 0.40 М Cr3+ 0.20 M Mn2+ 0.30 M Cr,0,2- 0.010 M H* 0.010 MH* The standard reduction potentials are as follows: MnO, + 8H* + 5e → Mn2+ + 4H,O, ɛ° = 1.51 V Cr,0,2- + 14H* + 6e 2Cr** + 7H2O, ɛ° = 1.33 V When current is allowed to flow, which species is oxidized? O Cr,0,²- Cr³+ MnO4 Mn2+ O H*arrow_forwardConsider the following standard reduction potentials in acid solution: Co2+ + 2e– ----> Co (s) E° = –0.28 V MnO4– + 8H+ + 5e– ---> Mn2+ + 4H2O E° = +1.51 V The strongest reducing agent listed above is:arrow_forwardRefer to the galvanic cell below (the contents of each half-cell are written beneath each compartment): Ni Ag 1.0 M Ni2+ 1.0 M Ag* The standard reduction potentials are as follow: Ni2+ + 2 e- → Ni(s), E° = -0.25 Ag* + e - Ag(s), E° = 0.7996 When current is allowed to flow, which species is oxidised? Select one: а. Ag b. Cannot be determined from the data given. C. Ni2+ O d. Ag* O e. Niarrow_forward
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