Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Phenylethanol can be oxidised to phenylethanal or phenylethanoic acid, depending on the reagents used (both the alcohol and the aldehyde are of interest for their antimicrobial properties, while the acid is used to treat type II hyperammonemia): A (a) (b) (c) CoH,CH,CHO phenylethanal B C6H5CH₂CH₂OHC₂H₂CH₂CO₂H phenylethanol Suggest reagents (shown as A and B in the scheme above) that could be used to carry out the oxidation of the alcohol to the aldehyde and the acid, respectively. C6H5CH₂- Suggest two other syntheses of phenylethanoic acid, in each case indicating the starting materials and other reagents required, but not giving details of mechanism. One of your proposed syntheses must start with a compound which only contains seven carbon atoms (the acid product contains eight carbon atoms). phenylethanoic acid Phenylethanal can be converted to a hydrate in the presence of aqueous acid, though the position of equilibrium is very far to the left: H H+/H₂O OH C6H5CH₂-C-H OH Explain why…arrow_forwardIsopropanol was treated with sodium metal, followed by 1-chloroheptane. What product formed? Group of answer choices an alcohol an alkene an ether an aldehydearrow_forwardDraw the structure(s) of the major organic product(s) of the following reaction. Draw a structural formula for the enol form of the carbonyl compound below.arrow_forward
- Fill in the missing starting materials, reagents, or major products of each reactionarrow_forwardThe following molecule belongs to a class of compounds called enediols; each carbon of the double bond carries an-OH group. Draw structural formulas for the a-hydroxyketone and the a-hydroxyaldehyde with which this enediol is in equilibrium. CH-OH a-Hydroxyaldehyde = C-OH= a -Hydroxyketone ČH3 An enediolarrow_forwardChoose the major organic product of the following reaction. 1) LIAIH4 ether 2) H20 OH OH OH OH b) d) NH OHarrow_forward
- Which combination of starting compounds should be chosen to prepare pentyl propanoate pentanoic acid and propanol pentanol and propanoic acid pentanol and pentanoic acid propanol and propanoic acidarrow_forwardDraw the products formed when phenol(C6H5OH) is treated with each reagent. Give an explanation. d. (CH3CH2)2CHCOCl, AlCl3 j. product in (d), then NH2NH2, – OHarrow_forward
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