Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Reaction Mechanism and Rate Law
For the reaction
2NO + Cl2
2NOCI
Match the appropriate rate law to each postulated mechanism.
A Rate =
K[NO]
B Rate = K[NO][Cl₂]
C Rate = k[Cl₂]
D Rate =
K[NO]²[Cl₂]²
E Rate = k[Cl₂]²
F Rate = K[NO]²[Cl₂]
G Rate =
H Rate =
K[NO]²
= k[NO][Cl₂]²
I None of the above
NO + Cl2
NOCI2
fast equilibrium
slow
fast
2NOCI 2 → NOCI 3 + NOCI
NOCI 3
NOCI + Cl2
NO + Cl2
NOCI 2
fast equilibrium
NOCI 2 + NO
>2NOCI
slow
2NON₂O2
fast equilibrium
N2O2 + Cl2 > 2NOCI slow
NO + Cl2
NOCI + CI
slow
CI + NO
NOCI
fast
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Transcribed Image Text:Reaction Mechanism and Rate Law For the reaction 2NO + Cl2 2NOCI Match the appropriate rate law to each postulated mechanism. A Rate = K[NO] B Rate = K[NO][Cl₂] C Rate = k[Cl₂] D Rate = K[NO]²[Cl₂]² E Rate = k[Cl₂]² F Rate = K[NO]²[Cl₂] G Rate = H Rate = K[NO]² = k[NO][Cl₂]² I None of the above NO + Cl2 NOCI2 fast equilibrium slow fast 2NOCI 2 → NOCI 3 + NOCI NOCI 3 NOCI + Cl2 NO + Cl2 NOCI 2 fast equilibrium NOCI 2 + NO >2NOCI slow 2NON₂O2 fast equilibrium N2O2 + Cl2 > 2NOCI slow NO + Cl2 NOCI + CI slow CI + NO NOCI fast
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