Question - The mass spectrum of ibuprofen is given below. Identify the fragments that produce peaks at 206, 161, 119 and 91 on the mass spectrum. 163 161 CH3 CH3 OH Labios 119 100 80 60 40 20 0 50 100 150 200 H3C 91 107117 206 0
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- Is the compound giving rise to the mass spectrum shown here more likely to contain sulfur, bromine, or chlorine? Explain. 100 80 - 60- 40 20 40 80 120 160 m/z Relative abundance -유Mass spectrometry is often used to both identify and quantify compounds. What is different between mass spectra with changing concentrations of a compound? How would you design a method (i.e. what would you need) to both identify and quantify a compound using mass spectrometry?. A compound made of C, H, and Cl shows two peaks on a mass spectrum, one at 52 u and the other at 50 u. What is a reasonable molecular formula for this compound? Assume that there are only 1H, 12C, 35Cl and37Cl in the compound
- Which of the following compounds gives this mass spectrum and explain why it is so?Which of the following formulae is consistent with a molecular ion of m/z 73 in a mass spectrometry experiment? O C3H8N2 O C4H11N O C4H10O O C3H5CIBenzoic acid produced which of the following mass spectra? Unknown A Unknown B MASS SPECTRUM 100 MASS SPECTRUM 100 80 80 60 60 40 40 20- 20- 0.0 0.04 20 0.0 40 120 - 80 m/z 160 40 60 a0 .m/z 100 120 140 NIST Chemistry WebBook (http://webbook.nist.gov/chemistry) NIST Chemistry WebBook thetp://webbook.rist.goulchemistry) Unknown D Unknown C MASS SPECTRUM MASS SPECTRUM 100 100 80 80 60 60 40 40 20 20 0.0 0.0 20 40 60 80 100 120 0.0 40 80 120 160 200 m/z m/z NIST Chemistry WebBook (http://webbook.nist.gov/chemistry) NIST Chemistry Weblook thetp//webbook.rist.govichemistry) Re htensty Rel. Intensity
- Draw the molecular ion (M) for this molecule formed in the mass spectrometer. H IIZ: H -e QHow would you use mass spectrometry to distinguish between chloroform (CHCl3) and deutorated chloroform (CDCl3)?1. Which one of the given compounds is consistent with the mass spectrum below? 100 40 20 10 20 25 30 35 40 5o 55 45 60 65 70 75 m/z Courtesy of SDBS: National Institute of Advanced Industrial Science and Technology A. CH,CH,CH(CH,), В. CH,CHOHCH,CH, C. CH,CH,OCH,CH, D. CH,CH,NHCH,CH, E. CH,CH,CH,CH, Relative htensity