Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question I.
Consider the reaction of 2-bromo-2-methylpropane with water, shown below, to answer the following
question(s).
CH3
H₂C-C-Br
CH3
CH3
Diagram 1: The first step of this reaction is shown below.
CH3
CH3
H₂C C+
H₂C-C Br
|
CH3
H₂C-C+
CH₂
H₂O
6
H
CH3
H
CH3
B
Diagram 2: The second and third steps of the reaction are shown below.
CH₂
CH₂
H₂C-C-01
CH₂
H₂C-C-
AH° = +44 kJ/mol
AS° = +0.12 kJ/K.mol
T = 298 K
Keq = 0.035
OH
CH
HC_C_07
CH₂
H
+
+
Br
1
HBr
ÖH₂
H
+
H₂O*
6) Based on all of the data presented in Question I, draw a qualitative reaction energy diagram
for the reaction of 2-bromo-2-methylpropane with water. The first step is the slowest step of the
reaction. Fully label the diagram, including the coordinates. Calculate AGº and describe whether
this reaction is favorable (exergonic) or unfavorable (endergonic) based on the energy diagram
and the following thermodynamic data:
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Transcribed Image Text:Question I. Consider the reaction of 2-bromo-2-methylpropane with water, shown below, to answer the following question(s). CH3 H₂C-C-Br CH3 CH3 Diagram 1: The first step of this reaction is shown below. CH3 CH3 H₂C C+ H₂C-C Br | CH3 H₂C-C+ CH₂ H₂O 6 H CH3 H CH3 B Diagram 2: The second and third steps of the reaction are shown below. CH₂ CH₂ H₂C-C-01 CH₂ H₂C-C- AH° = +44 kJ/mol AS° = +0.12 kJ/K.mol T = 298 K Keq = 0.035 OH CH HC_C_07 CH₂ H + + Br 1 HBr ÖH₂ H + H₂O* 6) Based on all of the data presented in Question I, draw a qualitative reaction energy diagram for the reaction of 2-bromo-2-methylpropane with water. The first step is the slowest step of the reaction. Fully label the diagram, including the coordinates. Calculate AGº and describe whether this reaction is favorable (exergonic) or unfavorable (endergonic) based on the energy diagram and the following thermodynamic data:
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