Q8: From the P-V diagrams below find the network for the cycle process of 1 mole gas at 27°C. A P (105Pa) 200 kPa P B 100 kPa 0.05m³ Isotherm 0.1m³ V 9.00 6.00 3.00 2 1 V (m³) 2.00 4.00 6.00

A heliumfilled toy balloon has a gauge pressure of 0.200 atm and a volume of 10.0 L. How much greater is the internal energy of the helium in the balloon than it would be at zero gauge pressure?

Does a gas become more orderly when it liquefies? Does its entropy change? If s, does the entropy increase or decrease? Explain your answer.

It is unlikely that a process can be isothermal unless it is a very slow process. Explain why. Is the same true for isobaric and isochoric processes? Explain your answer.

(a) Construct a table showing the macro states and all of the individual microstates for tossing 13 coins. (Use Table 15.5 as a guide.) (b) How many macro states are there? (c) What is the total number of microstates? (d) What percent chance is here of tossing 5 heads and 1 tail? (e) How much more likely are you to toss 3 heads and 3 tails than 5 heads and 1 tail? (Take me ratio of the number of microstates to find out.)

You have a particular interest in automobile engines, so you have secured a co-op position at an automobile company while you attend school. Your supervisor is helping you to learn about the operation of an internal combustion engine. She gives you the following assignment, related to a simulation of a new engine she is designing. A gas, beginning at PA = 1.00 atm, VA = 0.500 L, and TA = 27.0C, is compressed from point A on the PV diagram in Figure P19.31 (page 530) to point B. This represents the compression stroke in a fourcycle gasoline engine. At that point, 132 J of energy is delivered to the gas at constant volume, taking the gas to point C. This represents the transformation of potential energy in the gasoline to internal energy when the spark plug fires. Your supervisor tells you that the internal energy of a gas is proportional to temperature (as we shall find in Chapter 20), the internal energy of the gas at point A is 200 J, and she wants to know what the temperature of the gas is at point C. Figure P19.31

Unreasonable Results (a) How many moles per cubic meter of an ideal gas are there at a pressure of 1.001014N/m2 and at 0C ? (b) What is unreasonable about this result? (c) Which premise or assumption is responsible?

A 2.00-mol sample of a diatomic ideal gas expands slowly and adiabatically from a pressure of 5.00 atm and a volume of 12.0 L to a final volume of 30.0 L. (a) What is the final pressure of the gas? (b) What are the initial and final temperatures? Find (c) Q, (d) Eint, and (e) W for the gas during this process.

(a) What is the change in entropy if you start with 10 coins in the 5 heads and 5 tails macrostate, toss them, and get 2 heads and 8 tails? (b) How much more likely is 5 heads and 5 tails than 2 heads and 8 tails? (Take the ratio of the number of microstates to find out.) (c) If you were betting on 2 heads and 8 tails would you accept odds of 252 to 45? Explain Why or why not. Table 15.5 10Coin Toss MacrostateNumber of Microstates (W) Heads Tails 10 0 1 9 1 10 8 2 45 7 3 120 6 4 210 5 5 252 4 6 210 3 7 120 2 8 45 1 9 10 0 10 1 Total: 1024

Assume a sample of an ideal gas is at room temperature. What action will necessarily make the entropy of the sample increase? (a) Transfer energy into it by heat, (b) Transfer energy into it irreversibly by heat, (c) Do work on it. (d) Increase either its temperature or its volume, without letting the other variable decrease, (e) None of those choices is correct.