Q5(a) A system formed initially of 2 mol CO2, 5 mol H2 and 1 mol CO undergoes the reactions: (b) CO2 (g) + 3H2 (g) → CH3OH (g) + H2O (g) CO2 (g) + H2(g) -> CO (g) + H2O(g) Show an expression for the mole fractions as a function of reaction coordinates,&, of the reacting species for the two reactions. The following reaction reaches equilibrium at 773.15 K and 2 bar. 4HCl (g) + O2 (g) → 2H2O (g) + 2Cl2 (g) The system initially contains 5 mol HCI and 1 mol O2. Assuming that the standard heat of reaction is constant in the temperature range 273.15 K to 773.15 K and the reaction occurs in the ideal gas phase, determine: = Given; R 8.314 J/mol.K; AH° 298 O2 = AH° 298 Cl2 = 0 AG° 298 O2 AG° 298 Cl2 = 0 (i) The equilibrium constant, K. (ii) The degree of conversion,&, at equilibrium.

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