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- Provide the structure of the major product(s) for the following reaction. || Ch₂ hv Na, CH,OH NH₂ 11 a Predict the product for the following reaction. II III C III IV IVPredict the product(s) and provide the mechanism for each reaction below. What does each mechanism have in common?Predict the product(s) and provide the mechanism for each reaction below.
- A step in a synthesis of PGE1 (prostaglandin E1, alprostadil) is the reaction of a trisubstituted cyclohexene with bromine to form a bromolactone. Propose a mechanism for formation of this bromolactone and account for the observed stereochemistry of each substituent on the cyclohexane ring. Alprostadil is used as a temporary therapy for infants born with congenital heart defects that restrict pulmonary blood flow. It brings about dilation of the ductus arteriosus, which in turn increases blood flow in the lungs and blood oxygenation.When cis-2-decalone is dissolved in ether containing a trace of HCl, an equilibrium is established with trans-2-decalone. The latter ketone predominates in the equilibrium mixture. Propose a mechanism for this isomerization and account for the fact that the trans isomer predominates at equilibrium.Draw resonance structures of the intermediate carbocations in tire bromination of naphthalene, and account for the fact that naphthalene undergoes electrophilic substitution at Cl rather than C2.
- Aldehydes and ketones react with thiols to yield thioacetals just as they react with alcohols to yield acetals. Predict the product of the following reaction, and propose a mechanism:Predict the product(s) and provide the mechanism for each reaction below.Provide a major product for the reaction below: OH OH Conc H2SO4