Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Provide the name reaction associated with each reaction below:
Ph-CH2.CH3
1.
R-CO-CH3 + N2Ha/HO
Ans
2.
Me-CO-Me + Me-MgCl followed by workup --------→? Ans
3.
Ph-CO-Ph +
N2H4/HO"
Ph-CH2 Ph
Ans
4.
Ph-CO-H+ Ph-CO-H + NAOH --> Ph-CO-OH + PHCH2-OH Ans
5.
PHCHO + Ag(NH3)2/NAOH ----> ?? Ph-C)-OH +Ag (s)
Ans
6.
Ph-H + Ph-CO-Br ------> Ph-CO-Ph?
Ans
Provide the structure of the missing product or reagent/s for the following transformations
(6) Cyclobutanone + NaBH4
??
Ans
(7)
??
+ MeMgBr/workup -- Ph-CH(OH)-Ph
Ans
(8) 2-Propanone + Methanol (xs) + PTSA?
-----> ?Ans
(9) Ph-CO-CH3 subjected to Clemensen reaction
Ans
-------->
(10) Ph-CH(OH)-Ph+ PCC
--------> ??
Ans
(11) CH3-CHO+ KMNO4
------>?
Ans
(12) 2 Benzaldehyde + KOH
-------> ?
Ans
(13) ? + LIAIH4?
----------> Ph-CH2-OH
Ans
(14) Ph-CO-H + Zn/Hg/HCI
---------------> ?
Ans
(15) 2 mol of CH3-CO-CH3 +1 mol of NaOH ----> ?
Ans
(16)
Ph-CO-Ph + NH3 ?
Ans
17.
Synthesize Ph-CH (OH)-CH3 starting with benzene & any other reagent of choice.
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Transcribed Image Text:Provide the name reaction associated with each reaction below: Ph-CH2.CH3 1. R-CO-CH3 + N2Ha/HO Ans 2. Me-CO-Me + Me-MgCl followed by workup --------→? Ans 3. Ph-CO-Ph + N2H4/HO" Ph-CH2 Ph Ans 4. Ph-CO-H+ Ph-CO-H + NAOH --> Ph-CO-OH + PHCH2-OH Ans 5. PHCHO + Ag(NH3)2/NAOH ----> ?? Ph-C)-OH +Ag (s) Ans 6. Ph-H + Ph-CO-Br ------> Ph-CO-Ph? Ans Provide the structure of the missing product or reagent/s for the following transformations (6) Cyclobutanone + NaBH4 ?? Ans (7) ?? + MeMgBr/workup -- Ph-CH(OH)-Ph Ans (8) 2-Propanone + Methanol (xs) + PTSA? -----> ?Ans (9) Ph-CO-CH3 subjected to Clemensen reaction Ans --------> (10) Ph-CH(OH)-Ph+ PCC --------> ?? Ans (11) CH3-CHO+ KMNO4 ------>? Ans (12) 2 Benzaldehyde + KOH -------> ? Ans (13) ? + LIAIH4? ----------> Ph-CH2-OH Ans (14) Ph-CO-H + Zn/Hg/HCI ---------------> ? Ans (15) 2 mol of CH3-CO-CH3 +1 mol of NaOH ----> ? Ans (16) Ph-CO-Ph + NH3 ? Ans 17. Synthesize Ph-CH (OH)-CH3 starting with benzene & any other reagent of choice.
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