Answered: Propose a structure that fits the…

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter20: Carboxylic Acids And Nitriles

Section20.SE: Something Extra

Problem 33AP

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Propose a structure that fits the description: a 3-carbon ester, C3H6O2.
Compound A has the molecular formula C7H12. Hydrogenation of compound A produces 2-methylhexane. Hydroboration-oxidation of compound A produces an aldehyde. Draw the structure of compound A.
An organic compound is analyzed and found to contain 66.7% carbon, 11.2% hydrogen, and 22.1% oxygen by mass. The compound boils at 79.6 °C. At 100 °C and 0.970 atm, the vapor has a density of 2.28 g/L. The compound has a carbonyl group and cannot be oxidized to a carboxylic acid. Suggest a structure for the compound.
7. The following compounds are isomeric esters derived from acetic acid, each with formula C5H10O2. Draw the structures of the two esters?
When the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?
Formaldehyde, H2C=O, is known to all biologists because of its usefulness as a tissue preservative. When pure, formaldehyde trimerizes to give trioxane, C3H6O3, which, surprisingly enough, has no carbonyl groups. Only one monobromo derivative (C3H5BrO3) of trioxane is possible. Propose a structure for trioxane.
Draw the structures of the following compounds:(a) Ethanoic acid(b) Bromopentane(c) Butanone
Which of the following structural features could be found in a compound with formula C7H12?
Ketene, H2C=C=O, is an important industrial chemical. Predict the products that would be formed when ketene reacts with **hint: Markovnikov addition occurs. (a) ethanol (b) acetic acid (c) ethylamine.
Acetyl chloride, CH3COCl, reacts with the hydroxyl groupsof alcohols to form ester groups with the elimination ofHCl. When an unknown compound X with formulaC4H8O3 reacted with acetyl chloride, a new compound Ywith formula C8H12O5 was formed.(a) How many hydroxyl groups were there in X?(b) Assume that X is an aldehyde. Write a possible structure for X and a possible structure for Y consistent with your structure for X.
5.Write the structural formula of the ester that, when hydrolyzed, would yield the following:(a) methanol and propanoic acid(b) 1-octanol and acetic acid (c) ethanol and butanoic acid
Define Ethylene—C2H4 ?

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Propose a structure that fits the description: a nitrile, C3H5N.