, Problem 14: A pot containing 620 g of water is placed on the stove and is slowly heated from 18°C to 93°C. Calculate the change of entropy of the water in J/K. AS =||

An ideal gas is taken from an initial temperature Ti to a higher final temperature Tf along two different reversible paths. Path A is at constant pressure, and path B is at constant volume. What is the relation between the entropy changes of the gas for these paths? (a) SA SB (b) SA = SB (c) SA SB

Of the following, which is not a statement of the second law of thermodynamics? (a) No heat engine operating in a cycle can absorb energy from a reservoir and use it entirely to do work, (b) No real engine operating between two energy reservoirs can be more efficient than a Carnot engine operating between the same two reservoirs, (c) When a system undergoes a change in state, the change in the internal energy of the system is the sum of the energy transferred to the system by heat and the work done on the system, (d) The entropy of the Universe increases in all natural processes, (e) Energy will not spontaneously transfer by heat from a cold object to a hot object.

True or False: The entropy change in an adiabatic process must be zero because Q = 0.

An ice tray contains 500 g of liquid water at 0C. Calculate the change in entropy of the water as it freezes slowly and completely at 0C.

A sample of a monatomic ideal gas is contained in a cylinder with a piston. Its stale is represented by the dot in the PV diagram shown in Figure OQ22.9. Arrows A through E represent isobaric, isothermal, adiabatic, and isovolumetric processes that the sample can undergo. In each process except D, the volume changes by a factor of 2. All five processes are reversible. Rank the processes according to the change in entropy of the gas from the largest positive value to the largest-magnitude negative value. In your rankings, display any cases of equality.

Give an example of a spontaneous process in which a system becomes less ordered and energy becomes less available to do work. What happens to the system's entropy in this process?

A sample of a monatomic ideal gas is contained in a cylinder with a piston. Its state is represented by the dot in the PV diagram shown in Figure OQ18.9. Arrows A through E represent isobaric, isothermal, adiabatic, and isovolumetric processes that the sample can undergo. In each process except D, the volume changes by a factor of 2. All five processes are reversible. Rank the processes according to the change in entropy of the gas from the largest positive value to the largest-magnitude negative value. In your rankings, display any cases of equality. Figure OQ18.9

A Carnot engine operates in a Carnot cycle between a heat source at 550 and a heat sink at 20 . Find the efficiency of the Carnot engine.

(a) What is the change in entropy if you start with 10 coins in the 5 heads and 5 tails macrostate, toss them, and get 2 heads and 8 tails? (b) How much more likely is 5 heads and 5 tails than 2 heads and 8 tails? (Take the ratio of the number of microstates to find out.) (c) If you were betting on 2 heads and 8 tails would you accept odds of 252 to 45? Explain Why or why not. Table 15.5 10Coin Toss MacrostateNumber of Microstates (W) Heads Tails 10 0 1 9 1 10 8 2 45 7 3 120 6 4 210 5 5 252 4 6 210 3 7 120 2 8 45 1 9 10 0 10 1 Total: 1024