Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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- The following chart below is a plot of VLE data from the Dortmund data bank for a binary mixture of acetone (1) and isopropanol (2) at a constant temperature of 328.15 K. Values for the plot are also included in the table below. The saturated vapor curve is magenta, and the saturated liquid curve is cyan. Answer the following questions related to VLE. Pressure (kPa) c) 95 85 75 65 55 45 35 25 0 T=328.15 K 0.2 0.4 0.6 Mole fraction x1, y1 0.8 1 -P-x -P-y P (kPa) 30.30 34.393 39.93 44.208 52.026 59.05 60.848 69 X1 0 y₁ 0 0.0237 0.1166 0.0642 0.2777 0.0971 0.3625 0.1591 0.4762 0.2353 0.5722 0.2687 0.6024 0.3879 0.6995 71.177 0.4314 0.7284 75.068 0.5234 0.7655 80.287 0.6084 0.8098 85.038 0.7216 0.8617 85.942 0.7338 0.8729 0.8569 0.924 91.22 94.308 0.9214 0.9629 96.91 1 1 A superheated vapor of acetone and isopropanol with mole fractions y₁=0.36 and y2=0.64 is initially at 35 kPa pressure. What pressure must you increase this gas mixture to before it starts to condense? (Hint: you can…arrow_forwardPlease solve correctly, will provide helpful ratings. Thank youarrow_forwardEVALUATION OF MASS DIFFUSIVITY Find the diffusivity of CO, in N2 at 30°C and 740 mm Hg. Find the diffusivity of benzene vapor in air at 600C and 120 kPa Find the diffusivity of isopropyl alcohol in liquid water at 45°Carrow_forward
- I only want number 2 answered. The question is based on number onearrow_forwardQUESTION 3 Using AfGO given below at 25°C for the reactants and products to calculate the standard Gibbs energy AGO. Please enter your answer (unit: kJ/mol) with one decimal. for example, 100.345 is written as 100.3, and pay attention to the sign. AfGO (kJ/mol) SO2 (g) + 12 O2(g) SO3(g) -300.1 0 -374.2arrow_forwardRegarding the following reaction, A (s) + 2B (g) →→ C (1) + 3D (g) ArH(298K)=91.4kJ/mol where g, I, s - means gas, liquid and solid, respectively, and assuming all gases are perfect gas, calculate ArU(298K). Instruction: Please enter your answer (unit:kJ/mole) round to 2 decimal place.arrow_forward
- How many moles of oxygen gas must react completely to produce 1.57 moles of carbon dioxide according to the reaction: C3H8 + 5 O2 --> 3CO2 + 4H2O? Group of answer choices 0. 942 mol 2.62 mol 1.57 mol 4.71 mol 0.314 molarrow_forwardP.9 Assume that a sealed vessel at constant pressure of 1 bar initially contains 2.00 mol of NO₂(g). The system is allowed to equilibrate with respect to the reaction 2 NO₂(g) N₂O4(g). The number of moles of NO₂(g) and N₂O4(g) at equilibrium is 2.00 - 2 and , respectively, where is the extent of reaction. a. Derive an expression for the entropy of mixing as a func- tion of . b. Graphically determine the value of ₹ for which AS mixing has its maximum value. c. Write an expression for Gpure as a function of §. Use Equation 104 to obtain values of Gm for NO2 and N₂O4. d. Plot Gmixture = Gpure + AGmixing as a function of for ₹ T = 298 K and graphically determine the value of & for which Gmixture has its minimum value. Is this value the same as for part (b)?arrow_forward
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