Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Polarities of analyte functional group increase in the order of
hydrocarbon < ethers < esters < ketones < aldehydes < amides < amines < alcohols
Arrange the order of elution [from shortest to longest retention time] for the following six compounds from an HPLC C18 column.
C2H5OH
CH3COCH3
CH3COOH
CH3COOC2H5 C2H50C2H5
(СН3)2NH
O A. C2H5OH < CH3COOH < (CH3)2NH < CH3COCH3 < CH3COOC2H5 <C2H50C2H5
O B. CH3COOH <C2H5OH < (CH3)2NH < CH3COCH3 < CH3COOC2H5 <C2H50C2H5
O C. C2H5OH < CH3COOH < (CH3)2NH < CH3COCH3 < C2H50C2H5 < CH3COC2H5
O D. CH3COOH <C2H5OH < (CH3)2NH < CH3COCH3 < C2H50C2H5 < CH3COOC2H5
O E. CH3COOH <C2H5OH < (CH3)2NH < CH3COOC2H5 < CH3COCH3 <C2H50C2H5
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Transcribed Image Text:Polarities of analyte functional group increase in the order of hydrocarbon < ethers < esters < ketones < aldehydes < amides < amines < alcohols Arrange the order of elution [from shortest to longest retention time] for the following six compounds from an HPLC C18 column. C2H5OH CH3COCH3 CH3COOH CH3COOC2H5 C2H50C2H5 (СН3)2NH O A. C2H5OH < CH3COOH < (CH3)2NH < CH3COCH3 < CH3COOC2H5 <C2H50C2H5 O B. CH3COOH <C2H5OH < (CH3)2NH < CH3COCH3 < CH3COOC2H5 <C2H50C2H5 O C. C2H5OH < CH3COOH < (CH3)2NH < CH3COCH3 < C2H50C2H5 < CH3COC2H5 O D. CH3COOH <C2H5OH < (CH3)2NH < CH3COCH3 < C2H50C2H5 < CH3COOC2H5 O E. CH3COOH <C2H5OH < (CH3)2NH < CH3COOC2H5 < CH3COCH3 <C2H50C2H5
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