Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Please sketch the HOMO and LUMO of chloromethane.
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Step 1: Bonding and anti-bonding molecular orbitals

Molecular orbitals (MOs) are formed by the overlap of atomic orbitals (AOs) from individual atoms in a molecule. 

Bonding molecular orbitals are formed when the phase of the wave functions of the combining atomic orbitals is the same, leading to constructive interference. They contribute to the stability of the molecule and are lower in energy compared to the original atomic orbitals.

Antibonding molecular orbitals are formed when the phase of the wave functions of the combining atomic orbitals is opposite, leading to destructive interference. These are higher in energy compared to the original atomic orbitals.

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