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- OH - NH, Br2/KOH →product; 1. (a-hydroxy amide) Product of this Hoffmann bromamide reaction is : OH (a) Ph – Ĉ-CH3 (Ъ) Ph — CHO (c) Ph- CH3 (d) Ph – CH2 -NH2 NO2My C mentProblemID=192850292 A&P II Mast o ethyl butanoate ▼ PSY Connect Part A Pears Bb 1574 b Ansv G great H₂C NN Course Home pt My [ chem in career H 12D EXP CONT Predict the major organic product formed when the compound shown below undergoes a reaction with LiAlH4. Interactive 3D display mode CH3 Chen Chen Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Ter * I ο phys G phys N OPredict the product(s) for the following reaction. O ll + enantiomer I OI ||| OH O IV OH CN OH + enantiomer || 1. NaCN 2. H₂O CN "ОН + enantiomer ||| IV CN CN
- Among the choices shown, which reagents would lead to 3-pentanone from bromoethane? Al 1 Li Cul 2) C13CH2OTS | BI1 NECNn DMSO 2) CH3CH2M;Br 3)H2O C)CH13CH2-CO CI D CH3CH2-CO OCH2CI13The structure shown below is an intermediate in the synthesis of which biogenic amine? Use arrows to show how the next intermediate in this reaction is formed, and draw the structure of that intermediate. -CH,-C-coo HN N || CH HO CH,0 H,CLook at the three resonance structures of naphthalene shewn in Section 15-6, and account for the fact that not all carbon—carbon bonds have the same length. The C1-C2 bond is 136 pm long, whereas the C2—C3 bond is 139 pm long.
- N-Nitrosamines by themselves are not significant carcinogens. However, they are activated in the liver by a class of iron-containing enzymes (members of the cytochrome P-450 family). Activation involves the oxidation of a C-H bond next to the amine nitrogen to a C-OH group. OH ОН N=0 N=O Og 'N- H+ H N,+ cyt P-450 N-Nitroso- 2-Нydroxy-N- nitrosopiperidine An alkyl diazonium ion piperidine (a carcinogen) Show how this hydroxylation product can be transformed into an alkyl diazonium ion, an active alkylating agent and therefore a carcinogen, in the presence of an acid catalyst.Determine the major product(s) of the following reaction: (En: enantiomer) Bľ2 Br, ? H,O ОН A) + En Br Br В) + En Br ОН C) + En HQ Br YOH D) + EnO || CH3-CO-C-CH3 tCH3CH2CH, NH CH 3 | CH3-C-CL + CH3-N-CH3 Complete the following reaction.
- What is the expected major product for the following reaction sequence? OH OH + enantiometr 01 00 0 || OIV OV OsO4 (cat.) NMO 애 OH + enantiomer 11 OH + enantiomer ||| IV مة HO OH2) How would you synthesize the following compounds from cyclohexanone? CH₂Br CH₂C6H5 A Br B C D CH2CH2CO2Hthe structure of the major product of the following reaction is NaCN Br DMF CN CN CN A Oc OA 3.