Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. O A Br₂ CH₂OH 2. (CH3)2S B 1.03 2. DMS KMnO4, NaOH cold HI mCPBA A 1. Os04 2. H₂O₂ 78 16 15 CH₂CO3H (peroxyacid) 19 20 1 .MCPBA 3 H₂ Pd or Pt (catalyst) 12 2. H3O+ 11 10 Pd or Ni (catalyst) 2 ....OH OH OH doa doan da OH "OH OH D₂ (deuterium) EtOH Br₂ B HBr ROOR BH 3 THF Фәнхолда) H₂SO4 HCI 1. BH, THF 2. H₂O₂, NaOH Br₂ DIE Br₂ H₂O C OH da ""OH D OH OH OH OH OH dom dom dom œ œ "OH OH ""OH OH OH OH da OH

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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please predict the products for each of the following reactions.
Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).
If a mixture of enantiomers is formed, please draw all the enantiomers.
О А
O
O
B
Weite
C
D
CH.OH
Br₂
1.03
2. DMS
KMnO4, NaOH
cold
HI
mCPBA
A
1. Os04
2. H₂O₂
..OH
ďœ
OH
OH
18
17
""OH
16
15
CH₂CO3H
(peroxyacid)
19
14
13
MCPBA
20 1 2
12 11 10
2. H3O+
Pd or Ni (catalyst)
OH
OH
OH
your dom Joom
""OH
OH
"OH
D₂ (deuterium)
B
EtOH
Br₂
HO"
OH
HBr
ROOR
(peroxide
H₂SO4
HCI
BH 3 THF
1. BH, THF
2. H₂O₂, NaOH
Br₂
C
Br₂
H₂O
...OH
"""OH
A
OH
OH
D
....OH
OH
OH
Joom
OH
Transcribed Image Text:Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. О А O O B Weite C D CH.OH Br₂ 1.03 2. DMS KMnO4, NaOH cold HI mCPBA A 1. Os04 2. H₂O₂ ..OH ďœ OH OH 18 17 ""OH 16 15 CH₂CO3H (peroxyacid) 19 14 13 MCPBA 20 1 2 12 11 10 2. H3O+ Pd or Ni (catalyst) OH OH OH your dom Joom ""OH OH "OH D₂ (deuterium) B EtOH Br₂ HO" OH HBr ROOR (peroxide H₂SO4 HCI BH 3 THF 1. BH, THF 2. H₂O₂, NaOH Br₂ C Br₂ H₂O ...OH """OH A OH OH D ....OH OH OH Joom OH
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