Question 8Please predict the products for each of the following reactions.Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both).If a mixture of enantiomers is formed, please draw all the enantiomers.(CH3)2SBr2CH₂OH1.032. DMSKMnO4, NaOHcoldHIPd or Pt (catalyst)HBrROOR (peroxide)H₂O20131841716H₂SO4HCI1. BH3.THF2. H₂O2, NaOHBr2Br2H₂OBH3⚫THFMCPBA1. OsO42. H₂O2CH3CO₂H(peroxyacid)MCPBA1514139121110Pd or Ni (catalyst)D₂ (deuterium)OCH0DBď ďOHBrОНBrOH'Brď ď'OHBr'BrOHce caOHBrΑABCD

The given reaction is shown below.We have to provide the product of the given reaction.The given…

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br₂ CH₂OH 1.0 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH.COSH (peroxyacid) H₂O 17 16 15 14 20 12 11 10 deuterium) Pd or l (catalyst) Bra Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH, THF 2. H₂O2, NaOH Br2 H₂O BH, THF Br₂ 0 D A B ď ď ď ď OH Br OH Br OH OH Br ** 'Br OH 'Br OH ск Br A B C D

Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Br₂ CH₂OH 1.0 2. DMS KMnO4, NaOH cold HI MCPBA 1. OsO4 2. H₂O₂ CH.COSH (peroxyacid) H₂O 17 16 15 14 20 12 11 10 deuterium) Pd or l (catalyst) Bra Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O H₂SO4 HCI 1. BH, THF 2. H₂O2, NaOH Br2 H₂O BH, THF Br₂ 0 D A B ď ď ď ď OH Br OH Br OH OH Br ** 'Br OH 'Br OH ск Br A B C D

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter10: Oxidation And Reduction

Section: Chapter Questions

Problem 4CTQ

See similar textbooks

Similar questions

b) DRAW THE product of each of the following reactions? DRAW expected product stereochemistry, where NEEDED TO b) חוו H3C- Pd(OAc)2 Ag2CO3 dppe H OBn 1. B2H6, THF CH3 CH3 2. NaOH, H2O2 B 0
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. Question 5 2. (CH3)2S Br2 CH₂OH 1.03 2. DMS KMnO4, NaOH cold HI MCPBA Pd or Pt (catalyst) HBr ROOR (peroxide) H₂O 20 12 19 18 17 16 15 1. OsO4 2. H₂O2 CH3CO₂H 14 13 (peroxyacid) 12 11 10 H2SO4 HCI 5 1. BH3.THF 6 2. H₂O2, NaOH Br2 Pd or Ni (catalyst) D2 (deuterium) FIOH MCPBA 2. H₂O Br2 H₂O BH3⚫THF A B с D 8.8 A B C 3.8 ४.४
Give strucutre of products formed including stereochemistry if appropriate. If more than one product is formed, indicated which is the major product or if formed in equal amounts. PhMgBr (2 equiv.) then H30* HO, он он РСС но
Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. O O O A O Br₂ CH3OH A 1.03 2. DMS KMnO4, NaOH cold HI mCPBA 1. Oso4 2. H₂O2 1.03 S B 18 17 19 20 1 16 14 CH,CHOSH (peroxyacid) MCPBA Pd or Pt (catalyst) 13 12 11 2 10 3 Pd or Ni (catalyst) D₂ (deuterium) EtOH C HBr ROOR BH3 THF Фәнхолест a ada d œœœœœ H₂SO4 HCI 1. BH3-THF 2. H₂O2, NaOH Br₂ Br₂ H₂O D D
Please predict the products for each of the following reaction #3. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. *PLEASE CHOOSE ONE OF THE ANSWERS, A B C D
A E OH OH H This is a(n) OH R B F PCC, CH₂Cl₂ H type reaction. The major product if R = CH₂CH3 is compound The major product if R = H is compound G Look at the given reaction and use the letter code corresponding to each compound in the blank to indicate the expected product(s), or fill in the blank with the appropriate vocabulary word or phrase. If a specific stereoisomer (e.g single enantiomer) is formed, select that isomer only. If a mixture of stereoisomers (e.g. racemic or diastereomers) is formed, select the single structure that shows the appropriate mixture (e.g. lines not dashes). If we convert the reagent to Na2CrO4, H₂SO4, H₂O: The major product if R = CH₂CH3 is compound The maior product if R = H is compound ??? OH D H H though compound
Please fill in the missing reactants, reagents or products in the following reactions. Indicate relative stereochemistry where it is necessary CI j)
(j) Br HO- 25°C Draw the major product(s) of the reaction. Include all stereoisomers formed as part of the major product.
19) Give the products obtained from the following Wittig reaction. Show both stereoisomers. O || -CCH3 CH3CH₂ Ph .H Y" + Ph -P=C Ph Give the products for the following reaction. CH₂ CH3 K C₂H₂ CH₂ H + C₂H₂ CH3 ?
a Draw the structure of the intermediate (I) for the reaction below. Hg(O2CCH3)2 NaBH4 Product CH;OH H3C • Use the wedge/hash bond tools to indicate stereochemistry where it exists. If the reaction produces a racemic mixture, just drawv one stereoisomer.
Draw the predominant product(s) of the following reactions including stereochemistry when it is appropriate. (CH3)2CHCH2-CEC-H 1 HCI Consider E/Z stereochemistry of alkenes. • Do not show stereochemistry in other cases. If no reaction occurs, draw the organic starting material.
- Stereochemistry & regiochemistry + T -CEN