Part A Calculate the osmotic pressure of a solution containing 20.00 mg of hemoglobin in 13.4 mL of solution at 15 °C. The molar mass of hemoglobin is 6.5 x 104 g/mol. Express your answer in atmospheres. ► View Available Hint(s) II 17| ΑΣΦ ? atm

6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.

In a police forensics lab, you examine a package that may contain heroin. However, you find the white powder is not pure heroin but a mixture of heroin (C12H23O5N) and lactose (C12H22O11). To determine the amount of heroin in the mixture, you dissolve 1.00 g of the white powdery mixture in water in a 100.0-mL volumetric flask. You find that the solution has an osmotic pressure of 539 mm Hg at 25 C. What is the composition of the mixture?

6-74 An osmotic semipermeable membrane that allows only water to pass separates two compartments, A and B. Compartment A contains 0.9% NaCI, and compartment B contains 3% glycerol C3H8O3. (a) In which compartment will the level of solution rise? (b) Which compartment (if either) has the higher osmotic pressure?

The osmotic pressure of human blood is 7.6 atm at 37 C. What mass of glucose, C6H12O6, is required to make 1.00 L of aqueous solution for intravenous feeding if the solution must have the same osmotic pressure as blood at body temperature, 37 C?

Will red blood cells swell, remain the same size, or shrink when placed in each of the solutions in Problem 8-101? Classify each of the following solutions as hypotonic, isotonic, or hypertonic relative to red blood cells? a. 0.92%(m/v) glucose solution b. 0.92%(m/v) NaCl solution c. 2.3%(m/v) glucose solution d. 5.0%(m/v) NaCl solution

A compound has a solubility in water of 250 mg/L at 25C. Should this compound be characterized as a soluble or insoluble compound at 25C?

Starch contains CC, CH, CO, and OH bonds. Hydrocarbons have only CC and CH bonds. Both starch and hydrocarbons can form colloidal dispersions in water. Which dispersion is classified as hydrophobic? Which is hydrophilic? Explain briefly.

A tree is 10.0 m tall. (a) What must be the total molarity of the solutes if sap rises to the top of the tree by osmotic pressure at 20 C? Assume the groundwater outside the tree is pure water and that the density of the sap is 1.0 g/mL. (1 mm Hg = 13.6 mm H2O.) (b) If the only solute in the sap is sucrose, C12H22O11, what is its percent by mass?

6-67 Calculate the freezing points of solutions made by dissolving 1.00 mole of each of the following ionic solutes in 1000. g of H2O. (a) NaCI (b) MgCI2 (c) (NH4)2CO3 (d) AI(HCO3)3