Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Suppose 200.0 mL of 0.50 M HCl and 200.0 mL of 0.50 M NaOH, both initially at 25.0°C, are mixed in a thermos flask. When the reaction is complete, the temperature is 28.4°C. Assuming that the solutions have the same heat capacity as pure water, compute the heat released (in kJ).arrow_forwardA bomb calorimeter, or a constant volume calorimeter, is a device often used to determine the heat of combustion of fuels and the energy content of foods. In an experiment, a 1.4710 g sample of maleic acid (C4H4O4) is burned completely in a bomb calorimeter. The calorimeter is surrounded by 1159 g of water. During the combustion the temperature increases from 22.46 to 25.59 °C. The heat capacity of the calorimeter, not including the surrounding water, was determined in a previous experiment to be 852.2 J/°C. Assuming that no energy is lost to the surroundings, calculate the molar heat of combustion of maleic acid based on these data. Assuming that no energy is lost to the surroundings, what is the molar heat of combustion of maleic acid, based on these data? (in kJ/mol). C4H4O4(s) + 3O2(g) → 2 H2O(l) + 4 CO2(g) + Energyarrow_forwardSuppose 300 mL of 2.00 M HCl and 300 mL of 2.00 M NaOH, both initially at 23.0 celsius, are mixed in a thermos flask. When the reaction is complete, the temperature is 36.6 celsius. Assuming that the solutions have the same heat capacity as pure water, compute the heat released in kJarrow_forward
- make sure that the answer is in the correct number of significant digitsarrow_forward4 A chemical reaction is run in 450 grams of liquid water, resulting in the water increasing from a temperature of 15 °C to 95 °C. a. Use the equations in your textbook to calculate how much heat is absorbed by the water? b. What is the change in enthalpy for the system? c. What is the change in enthalpy for the surroundings?arrow_forwardA student followed the procedure in this experiment , using 29.5 mL of 2.41 molar HCl and 31.5 mL of 2.41 molar NaOH , with both solutions having an initial temperature of 21.9 °C. After mixing , a maximum temperature of 31.0 °C is measured . The final mass of the mixture was found to be 62.201 grams . For this problem , assume the specific heat of the solution is 4.18 J/g °C. What is the heat transferred by this reaction, in Joules?arrow_forward
- A total of 2.00 mol of a compound is allowed to react with water in a foam coffee cup and the reaction produces 156 g of solution. The reaction caused the temperature of the solution to rise from 21.00 to 24.70 degrees Celsius. What is the enthalpy of this reaction? Assume that no heat is lost to the surroundings or to the coffee cup itself and that the specific heat of the solution is the same as that of pure water. Enter your answer in kilojoules per mole of compound to three significant figures.arrow_forwardUse the References to access important values if needed for this question. A student determines the heat of dissolution of solid potassium bromide using a coffee-cup calorimeter of negligible heat capacity. When 6.36 g of KBr(s) is dissolved in 115.00 g of water, the temperature of the solution drops from 25.00 to 22.71 °C. Based on the student's observation, calculate the enthalpy of dissolution of KBr(s) in kJ/mol. Assume the specific heat of the solution is 4.184 J/g°C. AHdissolution = kJ/mol Submit Answer 5 question attempts remainingarrow_forwardThe molar heat of solution of a substance is found to be +21.38 kJ/mol. The addition of 0.100 mol of this substance to 1.000L of water initially at 40.0 degrees celsius results in a temperature decrease. Assume the specific heat of the resulting solution to be equal to that of pure water. Find the final temperature of the solution (Also assume that the heat capacity of the calorimeter is negligible).arrow_forward
- Determine the change in enthalpy (H, in J) transferred when 8.0 g of sucrose (C12H22O11)are dissolved in 92.0 g of water in a coffee cup calorimeter. The temperature of the solution changesfrom 15.0 °C to 14.7 °C Assume the process takes place at constant pressure, the masses areadditive, and the specific heat of the solution is 4.18 J/g∙°C.arrow_forwardThe enthalpy of combustion of methane gas, CH4(g), is about -9.0*102 kJ/mol. When methanegas reacts with O2(g), the products are carbon dioxide CO2(g) and water H2O(l). How much heatis released during the combustion of methane gas when 4.0 mols of O2(g) are consumed. Express your answer in kJ.A. 3.0*102 kJB. 6.0*102 kJC. 9.0*102 kJD. 12*102 kJE. 18*102 kJarrow_forwardTo treat a burn on his hand, a person decides to place an ice cube on the burned skin. The mass of the ice cube is 15.2 g, and its initial temperature is −13.9 ∘C. The water resulting from the melted ice reaches the temperature of his skin, 29.9 ∘C. How much heat is absorbed by the ice cube and resulting water? Assume that all of the water remains in the hand. Constants for water can be found in this table. Enthalpy of fusion 333.6 J/g 6010. J/mol Enthalpy of vaporization 2257 J/g 40660 J/mol Specific heat of solid H 2 O (ice) 2.087 J/(g·°C) * 37.60 J/(mol·°C) * Specific heat of liquid H 2 O (water) 4.184 J/(g·°C) * 75.37 J/(mol·°C) * Specific heat of gaseous H 2 O (steam) 2.000 J/(g·°C) * 36.03 J/(mol·°C) *arrow_forward
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