P2D.2 Starting from the expression Cp − CV = T(∂p/∂T)V(∂V/∂T)p, use the appropriate relations between partial derivatives (The chemist’s toolkit 9 in Topic 2A) to show that C C T V T V p ( / ) ( / ) p V p T 2 − = ∂ ∂ ∂ ∂ Use this expression to evaluate Cp − CV for a perfect gas.

P2D.2 Starting from the expression Cp − CV = T(∂p/∂T)V(∂V/∂T)p, use the appropriate relations between partial derivatives (The chemist’s toolkit 9 in Topic 2A) to show that C C T V T V p ( / ) ( / ) p V p T 2 − = ∂ ∂ ∂ ∂ Use this expression to evaluate Cp − CV for a perfect gas.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter1: Gases And The Zeroth Law Of Thermodynamics

Section: Chapter Questions

Problem 1.73E

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