8Order the transitions of a vibrational-rotational spectrum by their energy change. Use figure 9 on page 474.v=1v=0▬▬▬PHighestPR branch: (v=0, J = 1) to (v=1, J =2)PR branch: (v=0, J-0) to (v=1,J=1)Frequency, vPP branch: (v=0, J = 2) to (v=1, J =1)LowestFP branch: (v=0, J = 1) to (v=1, J =0)QQbranch: (v=0, J = 0) to (v=1, J =0)R

In the rotational-vibrational spectrum, the energy of a given state can be calculated as:…

Answered: Order the transitions of a…

Order the transitions of a vibrational-rotational spectrum by their energy change. Use figure 9 on page 474. v=1 v=0 сл 4320 50 4320 R Frequency, v

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter15: Introduction To Electronic Spectroscopy And Structure

Section: Chapter Questions

Problem 15.8E

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Question

8
Order the transitions of a vibrational-rotational spectrum by their energy change. Use figure 9 on page 474.
v=1
v=0
▬▬▬
P
Highest
PR branch: (v=0, J = 1) to (v=1, J =2)
PR branch: (v=0, J-0) to (v=1,J=1)
Frequency, v
PP branch: (v=0, J = 2) to (v=1, J =1)
Lowest
FP branch: (v=0, J = 1) to (v=1, J =0)
Q
Qbranch: (v=0, J = 0) to (v=1, J =0)
R

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Step 2: R branch (v=0, J=1) to (v=1, J=2)

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Step 3: R branch (v=0, J=0) to (v=1, J=1)

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Step 4: P branch (v=0, J=2) to (v=1, J=1)

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Step 5: P branch (v=0, J=1) to (v=1, J=0)

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Step 6: Q branch (v=0, J=0) to (v=1, J=1)

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Step 7: Order of Energy Change of the Transition- Highest to lowest

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