Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Question
thumb_up100%
Consider the following proposed elementary steps for a reaction.
Step-1: H2O2(aq) + I– (aq) --> H2O(l) + IO– (aq)
Step-2: H2O2(aq) + IO– (aq) --> H2O(l) + O2(g) + I– (aq)
In this mechanism,
(A) I– is a reactant and IO– is the product in the overall reaction.
(B) I– is a catalyst and IO– is the reaction intermediate;
(C) I– is the reaction intermediate, while IO– is a catalyst;
(D) I– and IO– are both reaction intermediate;
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution
Trending nowThis is a popular solution!
Step by stepSolved in 2 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The iodide-catalyzed decomposition of hydrogen peroxide is thought to proceed by a four-step mechanism: H2O2(aq) + I-(aq) --> HOI(aq) + OH-(aq) (slow)HOI(aq) + OH-(aq) --> H2O(l) + OI-(aq)OI-(aq) + H2O2(aq) --> HOOI(aq) + OH-(aq)HOOI(aq) + OH-(aq) --> H2O(l) + O2(g) + I-(aq) (a) If the first step of this mechanism is rate-determining (slow), choose the correct rate law for the overall process. Rate = k [HOI] [H2O2] Rate = k [H2O2]2 Rate = k [I-] [H2O2] Rate = k [H2O2]2 [H2O2] Rate = k [I-] [HOI] Rate = k [H2O2] [H2O2] (b) Choose the correct chemical equation for the overall process. HOI(aq) + OH-(aq) --> H2O(l) + OI-(aq) H2O2(aq) + I-(aq) --> HOI(aq) + OH-(aq) 2 H2O2(aq) --> 2 H2O(l) + O2(g) (c) Identify an intermediate in the reaction. H2O HOI H2O2 I- (d) Identify the catalyst in the reaction. H2O H2O2 HOI I- (e) Identify a reactant in the reaction. H2O2 HOI H2O I- (f) Identify a product in the reaction. HOI H2O H2O2 I-arrow_forward1.) The reaction A(aq) ---> B(aq) is a first order reaction with respect to A(aq). The concentration of A(aq) is reduced to 26.2 % of its initial value in 1.61 minutes. What is this reaction's half-life (in s)? 2.) The reaction A(aq) ---> B(aq) + C(aq) is a first order reaction. The half-life of A(aq) is 94.8 s at 25.0oC and its half-life is 65.6 s at 45.0oC. What is its half-life (in s) at 65.0oC? 3.) The half-life of 14C is 5730 years. A sample contains 90.8 % of the 14C that it would contain if it were still part of a living being. What is the age (in years) of this sample?arrow_forward11) The reversible reaction AB, first order in both direction, has rate equation dx =k, (a-x) - k₂x where a is the initial concentration of A, x is the concentration of B at dt time t, k₁ is the rate constant for forward reaction and k2 is the rate constant for reverse reaction. The initial condition is x(0)=0. Solve the given differential equation.arrow_forward
- An irreversible unimolecular reaction (A -> B) has a rate constant (k) equal to 0.46 s-1. What is the half-time (t1/2)? If at time “zero” the concentration of A is 28 mM, what is the concentration at 1.5 seconds? At 2.17 seconds? Specify your units. t1/2 = [A] at t1/2 = [A] = at t = 2.17 sarrow_forwardGive typed full explanation not a single word hand written otherwise leave itarrow_forwardThe below reaction was studied using integrated rate kinetics 2A 3B The below graphs were generated. © CHEM1212 JB [A] vs. Time In[A] vs. Time 12 04 02 14 200 100 sime (s Ume b) 1/[A] vs. Time 7000 s.000 4000 cme (s) Which of the below mechanisms is most consistent with this data? [ALMarrow_forward
- do a IR spectra analysis and draw the molecular structure. Provide a well-explained solution.arrow_forwardThe aqueous-phase decarboxylation of CH2NO2CO2H, CH2NO2CO2H CH3NO2(aq) + CO2(g), is studied at a certain temperature, giving the following data: Time (s) [CH2NO2CO2H] (M) 0.0e+00 0.100 1.0e-01 0.0466 2.0e-01 0.0217 3.0e-01 0.0101 4.0e-01 0.00473 Figure out whether this reaction is first-order or second-order with respect to the concentration of CH2NO2CO2H. Calculate the value of the rate constant. Pick the choice from below which gives the correct reaction order and value of the rate constant for this reaction.arrow_forwardThe rate of the reaction CH,COOC,H (ag) + оН (ад) — СH,COO "(аg) + Cән,ОН(ад) was measured at several temperatures, and the following data were collected: Temperature (°C) к(м+s-) 15 0.0521 25 0.101 35 0.184 45 0.332 Calculate the value of Eq by constructing an appropriate graph.arrow_forward
- The reaction 2 H₂O₂ --> 2 H₂O + O₂ follows the mechanism: Step 1: H₂O2 (aq) + I¯(aq) --> H₂O(1) + 10¯(aq) SLOW Step 2: 10 (aq) + H₂O2(aq) --> H₂O(1) + O2(g) + l'(aq) FAST What is the molecularity of Step 2? bimolecular cannot be determined unimolecular termoleculararrow_forward(a) A study was made of the effect of hydroxide ion, OH–, concentration on the rate for the following reaction: I–(aq) + OCl–(aq) ----------------> IO–(aq) + Cl–(aq) Experimental data: [I] [OCl–] [OH–] Rate M/sec 0.0013 0.012 0.1 9.4 x 10-3 0.0026 0.012 0.1 18.7 x 10-3 0.0013 0.006 0.1 4.7 x 10-3 0.0013 0.018 0.1 14.0 x 10-3 0.0013 0.012 0.05 18.7 x 10-3 0.0013 0.012 0.2 4.7 x 10-3 0.0013 0.018 0.2 7.0 x 10-3 Determine the rate law and the value of the rate constant, k.arrow_forwardshift 11:32 AM Thu Feb 23 tab Tap here or pull up for additional resources The activation energy for a particular reaction is 102 kJ/mol. If the rate constant is 1.35 x 10-4 s¹ at 318 K, what is the rate constant at 273 K? caps lock ! 1 Q A N 1 @ 2 W S # 3 X H E D $ 4 C R TI F % 5 T V A 6 Question 17 of 26 G Y B & 7 H U N 8 J I ( 9 K M 1 4 7 +/- ) 0 0 < - 9.2 gf Parrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY