One way to make coal “cleaner” is to gasify the coal into “city gas”. In a proposed molten-iron coal gasification process pulverized coal of up to 3 mm size is blown into a molten iron bath and oxygen and steam are blown in from the bottom of the vessel. Materials such as lime for settling the slag, or steam for batch cooling and hydrogen generation can be injected at the same time. The sulfur in the coal reacts with lime to form calcium sulfide, which dissolves into the slag. The process operates at atmospheric pressure and 1400 to 1500°C. Under these conditions, coal volatiles escape immediately and are cracked. The carbon conversion rate is said to be above 98% and the gas is typically 65 to 70% CO, 25 to 35% hydrogen, and less than 2% carbon dioxide. Sulfur content of the gas is less than 20 ppm. Assume that the product gas is 68% Co, 30% H2, and 2% CO2. Calculate the enthalpy change that occurs on the cooling of 1000 m3 of the gas at 1475 °C and 1 atm to 25°C and 1 atm.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
One way to make coal “cleaner” is to gasify the coal into “city gas”. In a proposed molten-iron coal gasification process pulverized coal of up to 3 mm size is blown into a molten iron bath and oxygen and steam are blown in from the bottom of the vessel. Materials such as lime for settling the slag, or steam for batch cooling and hydrogen generation can be injected at the same time. The sulfur in the coal reacts with lime to form calcium sulfide, which dissolves into the slag. The process operates at atmospheric pressure and 1400 to 1500°C. Under these conditions, coal volatiles escape immediately and are cracked. The carbon conversion rate is said to be above 98% and the gas is typically 65 to 70% CO, 25 to 35% hydrogen, and less than 2% carbon dioxide. Sulfur content of the gas is less than 20 ppm. Assume that the product gas is 68% Co, 30% H2, and 2% CO2. Calculate the enthalpy change that occurs on the cooling of 1000 m3 of the gas at 1475 °C and 1 atm to 25°C and 1 atm.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps

Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The