1 Covalent Bonding And Shapes Of Molecules 2 Alkanes And Cycloalkanes 3 Stereoisomerism And Chirality 4 Acids And Bases 5 Alkenes: Bonding, Nomenclature, And Properties 6 Reactions Of Alkenes 7 Alkynes 8 Haloalkanes, Halogenation, And Radical Reactions 9 Nucleophilic Substitution And Β-elimination 10 Alcohols 11 Ethers, Epoxides, And Sulfides 12 Infrared Spectroscopy 13 Nuclear Magnetic Resonance Spectroscopy 14 Mass Spectrometry 15 An Introduction To Organometallic Compounds 16 Aldehydes And Ketones 17 Carboxylic Acids 18 Functional Derivatives Of Carboxylic Acids 19 Enolate Anions And Enamines 20 Dienes, Conjugated Systems, And Pericyclic Reactions 21 Benzene And The Concept Of Aromaticity 22 Reactions Of Benzene And Its Derivatives 23 Amines 24 Catalytic Carbon-carbon Bond Formation 25 Carbohydrates 26 Lipids 27 Amino Acids And Proteins 28 Nucleic Acids 29 Organic Polymer Chemistry expand_more
1.1 Electronic Structure Of Atoms 1.2 Lewis Model Of Bonding 1.3 Functional Groups 1.4 Bond Angles And Shapes Of Molecules 1.5 Polar And Nonpolar Molecules 1.6 Quantum Or Wave Mechanics 1.7 A Combined Valence Bond And Molecular Orbital Theory Approach To Covalent Bonding 1.8 Resonance 1.9 Molecular Orbitals For Delocalized Systems 1.10 Bond Lengths And Bond Strengths In Alkanes, Alkenes, And Alkynes Chapter Questions expand_more
Problem 1.20P: Write the ground-state electron configuration for each atom. After each atom is its atomic number in... Problem 1.21P: Identify the atom that has each ground-state electron configuration. (a) 1s2 2s2 2p6 3s2 3p4 (b) 1s2... Problem 1.22P: Define valence shell and valence electron. Problem 1.23P: How many electrons are in the valence shell of each atom? (a) Carbon (b) Nitrogen (c) Chlorine (d)... Problem 1.24P Problem 1.25P Problem 1.26P Problem 1.27P: Write Lewis structures for these compounds. Show all valence electrons. None of them contains a ring... Problem 1.28P: Write Lewis structures for these ions. Show all valence electrons and all formal charges. (a) Amide... Problem 1.29P Problem 1.30P: Some of these structural formulas are incorrect (i.e., they do not represent a real compound)... Problem 1.31P: Following the rule that each atom of carbon, oxygen, and nitrogen reacts to achieve a complete outer... Problem 1.32P: Following are several Lewis structures showing all valence electrons. Assign formal charges in each... Problem 1.33P: Which statements are true about electronegativity? (a) Electronegativity increases from left to... Problem 1.34P: Why does fluorine, the element in the upper right comer of the Periodic Table, have the largest... Problem 1.35P: Arrange the single covalent bonds within each set in order of increasing polarity. (a) CH, O H, NH... Problem 1.36P: Using the values of electronegativity given in Table 1.5, predict which indicated bond in each set... Problem 1.37P Problem 1.38P: Use VSEPR to predict bond angles about each highlighted atom. Problem 1.39P: Use VSEPR to predict bond angles about each atom of carbon, nitrogen, and oxygen in these molecules. Problem 1.40P: Use VSEPR to predict the geometry of these ions. (a) NH2 (b) NO2 (c) NO2+ (d) NO3 Problem 1.41P Problem 1.42P Problem 1.43P: What is the meaning of the term tertiary (3) when it is used to classify alcohols? Draw a structural... Problem 1.44P: What is the meaning of the term tertiary (3) when it is used to classify amines? Draw a structural... Problem 1.45P: Draw structural formulas for (a) The four primary (1) amines with the molecular formula C4H11N. (b)... Problem 1.46P: Draw structural formulas for the three tertiary (3) amines with the molecular formula C5H13N. Problem 1.47P Problem 1.48P: Identify the functional groups in each compound. Problem 1.49P: Draw a three-dimensional representation for each molecule. Indicate which ones have a dipole moment... Problem 1.50P: Tetrafluoroethylene, C2F4, is the starting material for the synthesis of the polymer... Problem 1.51P: Which statements are true about resonance contributing structures? (a) All contributing structures... Problem 1.52P Problem 1.53P Problem 1.54P Problem 1.55P: Are the structures in each set valid contributing structures? Problem 1.56P: State the orbital hybridization of each highlighted atom. Problem 1.57P: Describe each highlighted bond in terms of the overlap of atomic orbitals. Problem 1.58P: Following is a structural formula of the prescription drug famotidine, marketed by McNeil Consumer... Problem 1.59P: Draw a Lewis structure for methyl isocyanate, CH3NCO, showing all valence electrons. Predict all... Problem 1.60P: What is the hybridization of the highlighted atoms in the following structures? What are your... Problem 1.61P: Using cartoon representations, draw a molecular orbital mixing diagram for a CO bond. In your... Problem 1.62P: In what kind of orbitals do the lone-pair electrons on the oxygen of acetone reside? Are they in the... Problem 1.63P: Draw the delocalized molecular orbitals for the following molecule. Are both bonds of the triple... Problem 1.64AP Problem 1.65AP: Each compound contains both ions and covalent bonds. Draw the Lewis structure for each compound.... Problem 1.66AP: Predict whether the carbon-metal bond in these organometallic compounds is nonpolar covalent, polar... Problem 1.67AP Problem 1.68AP: Phosphorus is immediately under nitrogen in the Periodic Table. Predict the molecular formula for... Problem 1.69AP: Draw a Lewis structure for the azide ion, N3. (The order of atom attachment is NNN, and they do not... Problem 1.70AP: Cyanic acid, HOCN, and isocyanic acid, HNCO, dissolve in water to yield the same anion on loss of... Problem 1.71AP: In Chapter 6, we study a group of organic cations called carbocations. Following is the structure of... Problem 1.72AP: Many reactions involve a change in hybridization of one or more atoms in the starting material. In... Problem 1.73AP: Following is a structural formula of benzene, C6H6, which we study in Chapter 21. (a) Using VSEPR,... Problem 1.74AP: Following are three contributing structures for diazomethane, CH2N2. This molecule is used to make... Problem 1.75AP: (a) Draw a Lewis structure for the ozone molecule, O3. (The order of atom attachment is OOO, and... Problem 1.76AP: The following two compounds are isomers; that is, they are different compounds with the same... Problem 1.77AP: In future chapters, we will encounter carbanionsions in which a carbon atom has three bonds and a... Problem 1.78AP format_list_bulleted