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Brevicomin, the aggregation pheromone of the western pine bark beetle, contains a bicyclic bridged ring system and is prepared by the acidcatalyzed cyclization of 6,7-dihydroxy-nonan-2-one.
a. Suggest a structure for brevicomin.
b. Devise a synthesis of 6,7-dihydroxynonan-2-one from 6-bromohexan-2- one. You may also use three-carbon alcohols and any required organic or inorganic reagents.
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- [17] H What is corect name of following? CH2CH3 HO CH3 Br 2R,35-2-brome. (2R,3S) 2-bromo-3-hydroxy pentane (2R,3R) 2-bromo-3-hydroxy pentane ((25,3S) 2-bromo-3-hydroxy pentane (01 اورا (S) 2-bromo-3-hydroxy pentane (2S,3R) 2-bromo-3-hydroxy pentane 3hr [18] Which of following compound will undergo solvolysis with methanol to yield the two shown? H3C OCH 3 CH3 CH3 OCH3 (a) (15,3S)-1-bromo-1,3-dimethyl-cyclohexane (b) (1R,3R)-1-bromo-1,3-dimethyl-cyclohexane (c) (15,3R)-1-bromo-1,3-dimethyl-cyclohexane (4) (1R)-1-bromo-1,3-dimethyl-cyclohexane (e) (15)-1-bromo-1,3-dimethyl-cyclohexane5. Write in the products. CH a) CH H20 H* Account for all the carbons. (C6HS)3P=CHCH2CH(CH3)2 b) acetaldehyde NaCN, H* butanal -> d) (CH3CH2)2CuLi ------> 5-phenyl-3-penten-2-one H2NNHC6HS 5-phenyl-3-penten-2-oneH3C₂ Br H₂O a. Enantiopure (1R, 3R)-3-Methylcyclohexanol b. Achiral 1-Methylcyclohexanol C. Racemic mixture (1R, 3R)- and (1S, 3S)-3-Methylcyclohexanol d. Diastereomeric mixture of (1R, 3R)- and (1S, 3R)-3-Methycyclohexanol
- app.101edu.co oudy @ 2 X V * UL Week 7: Panopto ||| 3 D E PII $ 4 R Rank these alkyl halides in order of increasing reactivity in an SN2 reaction. F 4x X UL LTU 7-1A F4 HHH % 5 T G 4, CI F5 A 6 4) Y X Question 16 of 24 F6 C|Chegg.com & 7 U F7 ★ A) III < | < || 8 B) || < | < ||| C) ||| < || < | D) || < ||| < | E) | < ||| < || PrtScn 1 FB X + Home ( 9 F9 O ) End 0 D 67 ENG F10 P PgUp Tp S ( D [ * O 6:15 PM 10/18/2022 PgDn + F12 0 SL 3Rank the following groups in order of priority from highest (1) to lowest (3). < < -COO- -CH3 -NHCH3What is the correct IUPAC name for the following molecule? Q Search NO₂ 00 Et app.hond 68
- 6. The product(s) of the following reaction dd blow di CH2-CH2 excess HBr is/are: CH2 CH2 heat Od Al () (A od Ocf D (CHPPCOK (CHPCON G)D CH;CH2OCH,CH3 HO CH;CH,CH,CH,OH and CH;CH,CH2CH,Br II H t mol boumol toubong soinm od o CH2-CHBR HO CH2 CH2 BrCH-CH,CH-Cн,ОН and BrCH,CH,CH-CH,Br CityCHCH COM III IV A) I B) П O II D) IV E) None of these HO CH CH'OHOrder the following in increasing priority A. -C, -CH, -OL B. -CH3, -CH2OH, -CH2CH3 C. -C≡CH, -CH゠CH2, -CH゠O3 - Which is the better method to synthesize n-propylbenzene? CH₂-CH3 -- Ja A) B) CH3CH₂-C-CI AICI; CH3CH₂-CH₂-Cl AIC13 CH₂ Zn (Hg) HC1 CH₂-CH₂ CH₂ CH₂-CH3
- II: Complete each of the following reactions by supplying the missing product or reagents: 1. C-CI Н20 + 2. CH3-C- -CH3 + H2O Heat, | OH 2 3. CH3-C- СН3-С— СІ | 4. CH3-CH2-C- -OCH2CH3 H2O H Heat 2 + 5. CH3-CH2-CH2-C-OH + CH3OH HE Heat .?4) НО ОН catalytic H+ (a bicyclic compound)10:29 0. O ? 86% AIATS For Two Year Medic. A 61 /180 (02:55 hr min Mark for Review When 2-Methylpropene undergoes oxidation in the presence of acidic K2Cr2O7, the products obtained are CH3 – CH + CO2 CH3 — СH — С—ОН-СО, CH, -C =0+CO2 +H2O CH3 CH; – CH2 – CH + CO2 + H20 Clear Response III