Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Diels–Alder reaction of a monosubstituted diene (such as CH2=CH–
CH=CHOCH3) with a monosubstituted dienophile (such as CH2=CHCHO)
gives a mixture of products, but the 1,2-disubstituted product often
predominates. Draw the resonance hybrid for each reactant, and use the
charge distribution of the hybrids to explain why the 1,2-disubstituted
product is the major product.

 

OCH3
OCH3
CHO
A
OCH,
CHO
CHO
1,2-disubstituted product
1,3-disubstituted product
major
minor
expand button
Transcribed Image Text:OCH3 OCH3 CHO A OCH, CHO CHO 1,2-disubstituted product 1,3-disubstituted product major minor
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