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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question
No object can travel faster than the
would appear evident that the uncertainty in the speed of
any object is at most 3 × 108 m s-1
.
(a) What is the minimum uncertainty in the position of an
electron, given that we know nothing about its speed
except that it is slower than the speed of light?
(b) Repeat the calculation of part (a) for the position of a
helium atom.
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- Calculate the de Broglie wavelength of the following. (a) An electron moving at a speed of 1.04×106 m s-1.(b) A proton moving at a speed of 1.04×106 m s-1.(c) A bullet with a mass of 14.1 grams moving at a speed of 1.08×103 m s-1.(a) Wavelength electron = m (b) Wavelength proton = m(c) Wavelength bullet = marrow_forwardThe work function of metal is the minimum energy required to produce photoelectric effect on that metal, and the work function for potassium metal is 220. kJ/mol (a) What is the minimum energy in Joules required to eject an electron from potassium metal? (b) What is the longest wavelength of light, in nanometers (nm), capable of producing photoelectric effect on potassium metal? (c) If the surface of a piece of potassium metal is shone with a green light having wavelength, 2. = 510. nm, what is the kinetic energy of the ejected electron? (d) What is the speed (in m/s) of the ejected electron? (Planck's constant, h= 6.626 x 10 34 J•s.; speed of light, c = 3.00 x 10° m/s; m = 9.11 x 10 ³1 kg; i ev = 1.60 x 10-19 J; 1J=1 kgm³/s²)arrow_forwardIt is interesting to speculate on the properties of a universe with different values for the fundamental constants.(a) In a universe in which Planck’s constant had the valueh =1 J s, what would be the de Broglie wavelength ofa 145-g baseball moving at a speed of 20 m s-1 ?(b) Suppose the speed of the ball from part (a) is known to lie between 19 and 21 m s-1. What is the smallest distance within which it can be known to lie?(c) Suppose that in this universe the mass of the electron is1 g and the charge on the electron is 1 C. Calculate the Bohr radius of the hydrogen atom in this universe.arrow_forward
- Suppose the average distance between the nucleus and the electron in a newly discovered 3s state is given by the ollowing equation: = ° v%47r³ dr, where the wavefunction /3, (r) = r · 3 Зар 27 Ino is independent of 0 and ø. Jse the integral x"e-kz dx = , to determine . Express your final answer in units of the Bohr radius ao and atomic number Z. In other words, if you get a final answer that is 2.3 times , enter 2.3 as your final answer.arrow_forwardOne of the emission lines of the hydrogen atom has awavelength of 93.07 nm. (a) In what region of the electromagneticspectrum is this emission found? (b) Determinethe initial and final values of n associated with this emission.arrow_forward(a) The position of an electron is known to within 14.4 Å (1.44×10- m). What is the minimum uncertainty in its velocity? m s- 1 S (b) Repeat the calculation of part (a) for a carbon atom. ms-1 Sarrow_forward
- Calculate the de Broglie wavelength of the following. (a) An electron moving at a speed of 1.07×10³ m sl. (b) A proton moving at a speed of 1.07×10³ m s-1. (c) A bullet with a mass of 5.06 grams moving at a speed of 1.02×10³ m s-'. (a) Wavelength electron (b) Wavelength proton (c) Wavelength bulletarrow_forward5)arrow_forwardQuantum mechanics predicts that the energy of the ground state of the H atom is –13.6 eV. Insight into the magni- tude of this quantity is gained by considering several methods by which it can be measured. (a) Calculate the longest wavelength of light that will ion- ize H atoms in their ground state. (b) Assume the atom is ionized by collision with an elec- tron that transfers all its kinetic energy to the atom in the ionization process. Calculate the speed of the electron before the collision. Express your answer in meters per second (m s-') and miles per hour (miles h-1). (c) Calculate the temperature required to ionize a H atom in its ground state by thermal excitation. (Hint: Recall the criterion for thermal excitation of an oscillator in Planck's theory of blackbody radiation is that hv z kµT.)arrow_forward
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