Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Most of the coal available in the United States is bituminous or "soft" coal, which contains as much as 5% sulfur by weight. When this coal is burned, the sulfur
reacts with oxygen to form sulfur dioxide gas. When the sulfur dioxide gas dissolves in raindrops, it forms sulfuric acid. This is how we get acid rain. Here is the
reaction that produces sulfur dioxide gas when soft coal is burned:
(s)+802(g)
880, (g)
Suppose an engineer decides to study the rate of this reaction. He prepares four reaction vessels with 112.8 g of solid sulfur and 49.4 g of oxygen gas each. The
volume and temperature of each vessel is shown in the table below.
olo
Arrange the reaction vessels in decreasing order of initial rate of reaction. In other words, select a "1" next to the vessel in which the engineer can reasonably
expect the initial rate of reaction to be highest, a "2" next to the vessel in which the initial rate of reaction would be next highest, and so on.
Ar
initial rate of
vessel
volume temperature
reaction
А
3.0 L
630. °СC
В
5.0 L
630. °C
2.0 L
640. °C
D
3.0 L
640. °C
v ?
1 (highest)
2
3
4 (lowest)
>
expand button
Transcribed Image Text:Most of the coal available in the United States is bituminous or "soft" coal, which contains as much as 5% sulfur by weight. When this coal is burned, the sulfur reacts with oxygen to form sulfur dioxide gas. When the sulfur dioxide gas dissolves in raindrops, it forms sulfuric acid. This is how we get acid rain. Here is the reaction that produces sulfur dioxide gas when soft coal is burned: (s)+802(g) 880, (g) Suppose an engineer decides to study the rate of this reaction. He prepares four reaction vessels with 112.8 g of solid sulfur and 49.4 g of oxygen gas each. The volume and temperature of each vessel is shown in the table below. olo Arrange the reaction vessels in decreasing order of initial rate of reaction. In other words, select a "1" next to the vessel in which the engineer can reasonably expect the initial rate of reaction to be highest, a "2" next to the vessel in which the initial rate of reaction would be next highest, and so on. Ar initial rate of vessel volume temperature reaction А 3.0 L 630. °СC В 5.0 L 630. °C 2.0 L 640. °C D 3.0 L 640. °C v ? 1 (highest) 2 3 4 (lowest) >
Expert Solution
Check Mark
Step 1

Mass of reactant is kept constant. So, initial rate of reaction depends on volume and temperature.

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