Methyl 4-iodobenzoate (IC6H4COOCH3) - finish this by assigning the bonds - IR (neat) \bar{v} (cm-1): 2949, 2922 (), 2852 (), 1713, 1585, 1454, 1437, 1393, 1377, 1285, 1273, 1115, 1007, 847, 827, 756;

The bond dissociation energy to break 2 C-C bond(s) in 1 mole of glycerol (HOCH2CH(OH)CH2OH, see image below) molecules is H -C H- Single Bond H C N H 432 411 346 N 386 305 167 459 358 201 142 C=C 602 C=0 799 Multiple C=C 835 C=0 1072 Bonds 615 494 C=N O=0 CEN 887 N=N 942 "Al vales in ka

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Another reagent that can be used to convert carboxylic acids into acid chlorides is phosphorus trichloride (PCI3), as shown in the scheme below. :0: :0: :ö: PCI2 + -PCI2 H. H :O: + НОРCI2 The mechanism, for the reaction, is shown above but the curved arrows and the formal charges, on the respective atoms, have been omitted. (a) Draw the missing curved arrows for each step (b) Supply any missing formal charges

2. For each molecule below, determine and write the formal charge on each atom that has one. Do any of the molecules have a net formal charge that is not zero? All unshared valence electrons are shown in these Lewis structures. (a) :Ö: H₂C-N-CH3 CH3 trimethylamine oxide (b) ozone (c) H-C-H methylene (d) H H₂C-C H ethyl radical

Using average bond enthalpies (linked above), estimate the enthalpy change for the following reaction: 2C0(g) + 02(g) 2CO2(g)

Convert the following line-bond structures into molecular formulas: (a) CH₂OH H H H H کی C= = с с C )-1 H (c) H、 N. с (=^ 0=C с FO Aspirin (acetylsalicylic acid) 0 )=0 с C C=0 OH H C || H CH3 ć с N Nicotine C 1 с с H HY C-C T H H CH3 )—I C H I I H (b) (d) HO H 4-C I HO HO H H₂ H-C C=0 Vitamin C (ascorbic acid) C=C CH₂OH C-O C C-C HO но| | H H OH OH Glucose H OH 11

H&C OH H₂SO₁ CH,CH,CH,C-CHCH, H,SO, H₁C Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default. + CH 20 H± 2D EXP. CONT. Z1 A [1] Marvin JS by ChemAxon ΔΟ 0 0 0 0 0 A e Copyright 2024 B H C N о S CI Br - P LL F

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