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- For each compound, give the product(s) expected from (1) HgSO4>H2SO4@catalyzedhydration and (2) hydroboration–oxidation.(a) hex-1-yneHow many alkenes could you treat with H2, Pd/C to prepare methylcyclopentane?For each compound, give the product(s) expected from (1) HgSO4>H2SO4@catalyzedhydration and (2) hydroboration–oxidation.(a) hex-1-yne (b) hex-2-yne
- .Which one of the following molecules can react as electrophile in reactions with alkenes? CH3OH NaCI HCI KCN NaCI O HCI O KCN O CH3OHFor each compound, give the product(s) expected from (1) HgSO4>H2SO4@catalyzedhydration and (2) hydroboration–oxidation. cyclodecyneProvide the structure of the product(s) with stereochemisty if appropriate. If multiple products indicate major product or if products are formed in equal amounts. If there is no reaction expected explain why. (a) OH HIO4 (the protecting group is remained) CHO H HOH2C OH (b) CHO -ОН NaCN # HO -H H -OH CH₂OH (c) CHO HO- -H HO -H NH₂OH 張一 H -OH H -OH CH₂OH i) Ba(OH)2 ii) MeOH, H₂SO4 NaOAc Ac₂0 NaOMe MeOH
- C17T04Q2945 Give the major product(s) of the following reaction. ? KMN04, H* heat OH CN OH There is no reaction under these conditions or the correct product is not listed here.If anhydrides react like acid chlorides with the nucleophiles, draw the products formed when each of the following nucleophiles reacts with benzoic anhydride [(C6H5CO)2O]: (a) CH3MgBr (2 equiv), then H2O; (b) LiAlH4, then H2O; (c) LiAlH[OC(CH3)3]3, then H2O.HC CH CH3CO2H H,SO, H3C-C-O-C=CH2 H HgSO, Acetylene Acetic Acid Vinyl acetate Acetylene reacts with acetic acid in the presence of H,SO4 and HgSO4 to yield vinyl acetate, a monomer used in the production of poly(vinyl acetate). The reaction mechanism includes the following steps: 1. Formation of a bridged mercurinium ion intermediate between Hg- and acetylene; 2. Addition of acetic acid to open the three-membered ring; 3. Proton transfer to solvent to give an organomercury vinyl ester3; 4. Addition of H to the alkene to form a carbocation; 2+ 5. Expulsion of Hg²+ to form the alkene. Diagram the mechanism on a separate sheet of paper, and then draw the structure of the product(s) of step 3. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Draw organic species only. • Do not include counter-ions, e.g., Na, I, in your answer.
- Which of the following reactions does not proceed? O Dehydration of 2-propanol with H;SO, catalyst Hydrogenation of benzene with H2/Pt o Oxidation of 2-propanol by H,Cro O Hydrobromination of 2-butene with HBr O Hydration of cyclohexene with H2O/H2SO4Consider the following mechanism of reaction: CH3 CH, CH3 CH;C CH, + H-CI CH;CCH, + C: → CH;CCH, tert-butyl cation CI tert-butyl chloride In this reaction: The alkene and the carbocation intermediate are both nucleophilic HCl and CI" are both nucleophilic The alkene and HCI are both electrophilic The carbocation and CI" are both electrophilic The alkene and CI" are both nucleophilic AMeving to another question will save this responseProvide the structure of the organic products(s), which result in the reaction below. (Hint: it's a substitution product; show stereochemistry joll| CI CH3 Br CH3CH₂OH CN