Knowing that the extraction efficiency of an organic solvent over an aqueous solution can be measured by the following relationship: [A]i (Vaq / Vorg K+ Vaq)' · [A]o a. Compare the fraction of propanoic acid (C3H6O2) that can will remain in the aqueous solution after one extraction if 50.00 mL of the aqueous solution is extracted by 100.00 mL of heptane for which the KD value over water is 5.5. b. What will be this fraction of propanoic acid if the 100 mL are replaced by 4 volumes of 25.00 mL of heptane in four consecutive extractions? c. Is it more effective to adjust the aqueous solution to pH 3.0 or pH 8.0? Why?

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Chapter1: Chemical Foundations
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Knowing that the extraction efficiency of an organic solvent over an aqueous
solution can be measured by the following relationship:
[A]i
(Vaq / Vorg K+ Vaq)' [A]o
a. Compare the fraction of propanoic acid (C3H6O2) that can will remain in the
aqueous solution after one extraction if 50.00 mL of the aqueous solution is
extracted by 100.00 mL of heptane for which the Kp value over water is 5.5.
b. What will be this fraction of propanoic acid if the 100 mL are replaced by 4
volumes of 25.00 mL of heptane in four consecutive extractions?
c. Is it more effective to adjust the aqueous solution to pH 3.0 or pH 8.0? Why?
Transcribed Image Text:Knowing that the extraction efficiency of an organic solvent over an aqueous solution can be measured by the following relationship: [A]i (Vaq / Vorg K+ Vaq)' [A]o a. Compare the fraction of propanoic acid (C3H6O2) that can will remain in the aqueous solution after one extraction if 50.00 mL of the aqueous solution is extracted by 100.00 mL of heptane for which the Kp value over water is 5.5. b. What will be this fraction of propanoic acid if the 100 mL are replaced by 4 volumes of 25.00 mL of heptane in four consecutive extractions? c. Is it more effective to adjust the aqueous solution to pH 3.0 or pH 8.0? Why?
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