It turns out van der Waals was very careful when “designing” the van der Waals equation: P = [RT / (Vm−b)] − (a / V^2m). If you’re not sure, let’s see why he divided the "a" term by V^2m and not Vm. Specifically, can you calculate the residual volume of an alternative equation of state: P = [RT / (Vm − b)] − (a / Vm) and show that the residual volume is -∞ L/mol
It turns out van der Waals was very careful when “designing” the van der Waals equation: P = [RT / (Vm−b)] − (a / V^2m). If you’re not sure, let’s see why he divided the "a" term by V^2m and not Vm. Specifically, can you calculate the residual volume of an alternative equation of state: P = [RT / (Vm − b)] − (a / Vm) and show that the residual volume is -∞ L/mol
Physics for Scientists and Engineers with Modern Physics
10th Edition
ISBN:9781337553292
Author:Raymond A. Serway, John W. Jewett
Publisher:Raymond A. Serway, John W. Jewett
Chapter41: Atomic Physics
Section: Chapter Questions
Problem 45AP
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It turns out van der Waals was very careful when “designing” the van der Waals equation: P = [RT / (Vm−b)] − (a / V^2m). If you’re not sure, let’s see why he divided the "a" term by V^2m and not Vm. Specifically, can you calculate the residual volume of an alternative equation of state: P = [RT / (Vm − b)] − (a / Vm) and show that the residual volume is -∞ L/mol
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