Is it possible to use spectroscopic techniques to confirm both 4 He and 3 He in a sample of helium? Think about a singly - ionized atom He and select an electronic transition of this hydronic atom that is seen in the visible range). Compute the resolution (absolute and relative) that instrumentation has to provide to distinguish the two isotopes and to allow quantitative (!) determination of content.

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2. ] You make 150.0 mL of a copper(II) sulfate solution but forget to cover it before leaving for the day. The next class, you measure the volume and find that you only have 132.0 mL remaining. You didn’t record the initial concentration, but you measure the absorbance of the remaining solution at 620 nm and find that it is 0.386. You also construct the following calibration curve for CuSO4: Standard solution Abs620 0.50 M 0.424 0.40 M 0.336 0.30 M 0.247 0.20 M 0.159 (refer to image) a. What is the value for k (in Beer’s Law)? Provide a calculation or graph to support your answer. b. What is the concentration of the (remaining) solution? c. What was the concentration of the original solution from the first class? d. If you removed 7.5 mL from the 132.0 mL solution in the process of measuring the absorbance, how much water should you add to obtain the original concentration that you solved for in part (c)?

Be sure to answer all parts. Covalent bonds in a molecule abso rb radiation in the IR region and vibrate at characteristic frequencies. (a) A molecular vibration absorbs radiation of wavelength 176 µm. What frequency (in s) corresponds to that wavelength? Enter your answer in scientific notatio n. X 10 -1 (b) A molecular vibration has a frequency of vibration of 6.753 x 10 m) corresponds to that frequency? 13 Hz. What wavelength (in p IIO $4 %23 2 4 3. 7. e p

Assume for the following situations that Beer’s law remains linear. For (a) and (b), indicate whether the extinction coefficient ε, path length b, or concentration C is changing, and how it will change the absorbance of the solution. (a) A sample is moved from a test tube that is 1.0cm wide to a test tube that is 1.5cm wide. (b)  A sample is diluted by adding enough solvent to double its volume. (c)  A solution of iron (III) chloride appears brown when in high enough concentrations. In a 1.0 cm cuvet, the absorbance of 334 nm light by a 5.4 × 10−4 M solution of FeCl3 is measured to be 1.05. What is the extinction coefficient of the FeCl3 complex at this wavelength? (d)  A sample containing an unknown concentration of FeCl3 is measured to have an ab- sorbance of 0.43 at 334 nm in a 1.0 cm cuvet. What is the molar concentration of the solution?

If the plant poduces 1.6*10- kg(1600 metric ton) of Cl2 daily, estimate the quanties of H2 produced  2NaCl(aq) + 2H2O(l)--> 2NaOH(aq) + H2 (g) + Cl2 (g)

Assume for the following situations that Beer’s law remains linear. For (a) and (b), indicate whether the extinction coefficient ε, path length b, or concentration C is changing, and how it will change the absorbance of the solution. (a) A sample is moved from a test tube that is 1.0 cm wide to a test tube that is 1.5 cm wide. 4 (b) A sample is diluted by adding enough solvent to double its volume. (c) A solution of iron (III) chloride appears brown when in high enough concentrations. In a 1.0 cm cuvet, the absorbance of 334 nm light by a 5.4 × 10−4 M solution of FeCl3 is measured to be 1.05. What is the extinction coefficient of the FeCl3 complex at this wavelength?

1:25 A O * N 5GUC I 67%, Show What You Know: Learning... KO> O 8 de 8 A new band sensation is playing a concert and recording it for a live album to be released this summer. The band asks the sound mixer if he can autotune the singer who has a habit of singing slightly lower than the note. What would the mixer need to do to the sound wave? How would it affect the characteristics of the wave? В I |Revisión 田 !!!

During your experiment, you measure the absorbance of a sample to be 1.362. You have to convert thisabsorbance to methylene blue concentration (in ppm) using the absorbance measurements of two standardsolutions of known concentration:5 ppm: Absorbance 0.55510 ppm: Absorbance 1.211What is, in ppm, the concentration of your sample? Report using 3 decimal figures. Your answer must becorrect to 0.02 ppm

A chemist obtained the following data for percent lindane in the triplicate analysis of an insecticide preparation: 7.23, 6.95, and 7.53%. Calculate the 90% confidence interval for the mean of the the three data, assuming that  (a) the only information about the precision of the method is the precision for the three data.  (b) on the basis of long experience with the method, it is believed that s---->σ lindane.  (c) If s=0.28 is good estimate of σ, how many replicate measurement should be made in order for the mean for the analysis of sample to be within 0.2% of the true mean 90% of the time.