In the electron paramagnetic resonance spectrum ofthe propyl radical, C3H5, the hyperfine splitting constant is1.45 mT for coupl ing to the protons on the terminal carbonatoms and 0.406 mT for coupl ing to the protons attached tothe central carbon atom. Taking 0= 2.25 mT, use the McConnellequation to estimate the unpaired electron density on eachcarbon atom.
In the electron paramagnetic resonance spectrum ofthe propyl radical, C3H5, the hyperfine splitting constant is1.45 mT for coupl ing to the protons on the terminal carbonatoms and 0.406 mT for coupl ing to the protons attached tothe central carbon atom. Taking 0= 2.25 mT, use the McConnellequation to estimate the unpaired electron density on eachcarbon atom.
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter16: Introduction To Magnetic Spectroscopy
Section: Chapter Questions
Problem 16.34E
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In the electron paramagnetic resonance spectrum of
the propyl radical, C3H5, the hyperfine splitting constant is
1.45 mT for coupl ing to the protons on the terminal carbon
atoms and 0.406 mT for coupl ing to the protons attached to
the central carbon atom. Taking 0= 2.25 mT, use the McConnell
equation to estimate the unpaired electron density on each
carbon atom.
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