Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- In a study of the gas phase decomposition of hydrogen iodide at 700 K HI(g) →½ H2(g) + ½ I2(g) the following data were obtained: HI], M seconds 1.01 0.505 0.253 0.127 1.05x103 3.15x103 7.32x103 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 1.01 M is s and when the starting concentration is 0.505 M is S. (2) The average A(1/[HI]) / At from t= 0 s to t= 1.05x103 s is The average A(1/[HI]) / At from t= 1.05×103 s to t= 3.15×103 s is Ms!. (3) Based on these data, the rate constant for this order reaction isarrow_forwardIn a study of the decomposition of ammonia on a tungsten surface at 1100 °C NH3- →1/2 N₂ + 3/2 H₂ the following data were obtained: [NH3], M seconds 6.33x10-3 3.17x10-3 1.59x10-3 440 661 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 6.33x10-³ M is starting concentration is 3.17x10-³ M is (4) Based on these data, the rate constant for thi 7.95x10-4 S. (2) The average rate of disappearance of NH3 from t = 0 s to t = 440 s is ✓ 772 (3) The average rate of disappearance of NH3 from t = 440 s to t = 661 s is zero first second order reaction is M s-¹. M s-¹. M s-¹. Is and when the Previous Nexarrow_forwardThe following data are for the decomposition of hydrogen peroxide in dilute sodium hydroxide at 20 °C. H2₂O₂(aq) > H₂O(l) + 12 O₂(g) [H₂O₂], M time, min 7.34x10-2 0 3.67x10-2 8.68 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is (2) Based on these data, the rate constant for this 1.84x10-2 9.20x10-3 17.4 min. 26.0 order reaction is min -1arrow_forward
- The following data are for the gas phase decomposition of sulfuryl chloride at 600 K.SO2Cl2(g) SO2(g) + Cl2(g) [ SO2Cl2 ], M 3.73×10-3 1.87×10-3 9.35×10-4 4.68×10-4 time, min 0 203 406 609 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is ________ min .(2) Based on these data, the rate constant for this _______(zero, first, or second) order reaction is __________min-1.arrow_forwardFor the gas phase decomposition of phosphine at 120 °C 4 PH3 (9) → P4 (9)+ 6 H₂ (9) the following data have been obtained: [PH3], M time, s 0 The average rate of disappearance of PH3 over the time period from t = 0s to t = 23.0 s is 0.0644 0.0426 0.0281 0.0186 23.0 46.0 69.0 M/s.arrow_forwardThe rate constant for a given reaction is k = 0.312 M1s1. If the initial concentration of reactant is 1.00 M, the what is the length of the third half-life (in seconds)?arrow_forward
- The following data are for the decomposition of nitramide in aqueous solution at 25 °C. NH,NO2(aq) → N20(g) + H20(1) [ NH2NO2 ], 0.802 0.401 0.201 0.101 M time, min 175 350 525 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is min . (2) Based on these data, the rate constant for this O order reaction is min -1arrow_forwardIn a study of the gas phase decomposition of dinitrogen pentoxide at 335 K N2O5(g)2 NO,(g) + ½ O2(g) the concentration of N2O5 was followed as a function of time. It was found that a graph of In[N,O3] versus time in seconds gave a straight line with a slope of -7.38×10-3 s and a y-intercept of -3.13. Based on this plot, the reaction is | order in N2O5 and the half life for the reaction i | seconds.arrow_forwardIn a study of the gas phase decomposition of hydrogen iodide at 700 K HI(g)- →½ H2(g) + ½ I2(g) the following data were obtained: [HI], M seconds 1.48 0.740 0.370 0.185 750 2.25x103 5.25x103 Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 1.48 M is 750 s and when the starting concentration is 0.740 M is 1500 S. (2) The average A(1/[HI]) / At from t = 0 s to t = 750 s is M-1 s-1. The average A(1/[HI]) / At from t 750 s to t = 2.25×103 s is M-1 s-1. (3) Based on these data, the rate constant for this 0 order reaction is M-1 s-1.arrow_forward
- In a study of the decomposition of nitramide in aqueous solution at 25 °C NH2NO2(aq)N20(g) + H20(1) the concentration of NH2NO2 was followed as a function of time. It was found that a graph of In[NH,NO2] versus time in seconds gave a straight line with a slope of -6.72x105 s and a y-intercept of -0.911 . Based on this plot, the reaction is | reaction is |order in NH2NO2 and the half life for the seconds.arrow_forwardThe following data are for the gas phase decomposition of sulfuryl chloride at 600 K. sO,C2(g)- - SO2(g) + Cl2(g) [ SO;Clz ], M 2.89x103 1.45x103 7.25x104 3.63x104 time, min 168 336 504 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is | min. (2) Based on these data, the rate constant for this order reaction is minarrow_forwardIn a study of the decomposition of nitrous oxide at 565 °C N2₂O(g) N₂(g) + ½ O₂(g) the following data were obtained: [N₂0], M seconds 0.750 0 0.375 1.50x10³ 0.188 4.47x10³ Hint: It is not necessary to graph these data. (1) The observed half life for this reaction when the starting concentration is 0.750 M is concentration is 0.375 M is S. (2) The average A(1/[N₂0])/ At from t = 0 s to t = 1.50x10³ s is The average A(1/[N₂0])/ At from t = 1.50x10³ s to t = 4.47x103 s is (3) Based on these data, the rate constant for this 9.40×10-2 1.04x104 M-1 S-1. order reaction is M-1 S-1. M-¹ S-1. s and when the startingarrow_forward
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