Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A possible mechanism for the reaction described by:

CO(g) + Cl2(g) → COCl2(g)

Identify any intermediate species + write the rate law for each step.

*I'm confused on how to identify intermediate species and why the rate law for 2 = k2[Cl]2

 

Answers: Cl(g) and COCl(g) are intermediate species. The rate laws are k1[Cl2], k2[Cl]2, k3[Cl][CO], and k4[COCl][Cl2], respectively.

is the following four-step mechanism:
k,
Cl, (g)
→ 2 Cl(g)
→ Cl,(g)
(1)
(2)
k2
2 CI(g)
kg
Cl(g) + CO(g)
→ COCI(g)
→ COCI,(g) + Cl(g)
(3)
(4)
k4
COCI(g) + Cl2(g)
Identify any intermediate species and write the rate law for each step.
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Transcribed Image Text:is the following four-step mechanism: k, Cl, (g) → 2 Cl(g) → Cl,(g) (1) (2) k2 2 CI(g) kg Cl(g) + CO(g) → COCI(g) → COCI,(g) + Cl(g) (3) (4) k4 COCI(g) + Cl2(g) Identify any intermediate species and write the rate law for each step.
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