
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Transcribed Image Text:I. Below is some data on equilibrium constants at varying pressures and different
temperatures.
P/P
0.000197
0.001
0.01
0.1
1
10
20
30
40
50
G Urea (Scheme 1)
(T=413.15 K)
3.705-107
1.434 106
1.428.105
1.423 10²
1.417
1.411-10-²
3.525-10-3
1.566-10-3
0.88-10-3
0.563 10-3
G CO₂ (Scheme 2)
(T=453.15 K)
2.19 10-9
1.11.10-8
1.11.10-7
1.11.10-6
1.11.10-5
1.11.10 4
2.22-10-4
3.33 10 4
4.44-10-4
5.55-10-4
P/P is the ratio of reaction pressure to the standard pressure 101,325 Pa.
How does each reaction's equilibrium change with pressure?
J. Propose a set of conditions for reaction 2, including temperature, pressure, and starting
amounts, that will maximize the CO₂ reacted. Use an argument with the claim-evidence-
reasoning structure described above. Claim should include conditions, evidence can be
data provided plus any extra calculations/models you did, and reasoning should explain
to me how the data support your claim.
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