Answered: I need help to find the mechansim for…

I need help to find the mechansim for Preparation of Cyclohexanone by Na2CrO3/H2SO4 and explain the mechanisms step by step so I can understand it please

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter22: Carbonyl Alpha-substitution Reactions

Section22.SE: Something Extra

Problem 26MP: Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium...

See similar textbooks

Related questions

Q: Draw thee other resonance structures for the following carbocation. Use electron pushing arrows in…

A: Resonance occurs when p orbital on three or more neighboring atoms can overlap due to resonance it…

Q: A chemist dissolves 450. mg of pure hydroiodic acid in enough water to make up 50. mL of solution.…

A: Mass of hydroiodic acid = 450 mg

Q: An analytical chemist is titrating 92.2mL of a 0.4800M solution of piperidine C5H10NH with a…

A: Given;

Q: 4. Given the following reaction: 3 Cu + 8 HNO3 → 3 Cu(NO3)2 + 2 NO + 4 H₂O a) How many moles of…

A: A balanced chemical equation contain equal number of atoms of each elements on both sides of the…

Q: Calculate the solubility at 25 °C of CuBr in pure water and in 0.067 M Nal. You'll probably find…

Q: The boiling point of ethanol (C₂H5OH) is 78.5 °C. What is the boiling point of a solution of 12.4 g…

A: The question is based on the concept of colligative properties. we need to calculate boiling point…

Q: If a compound is 36.0% calcium and 64.0% chlorine by mass, what is the emperical foumla?

Q: A 6.00 L tank at 10.1 °C is filled with 7.51 g of boron trifluoride gas and 2.21 g of carbon dioxide…

A: It is based on the concept of mole fraction and Dalton's law of partial pressure Here we are…

Q: Calculate the total number of atoms contained within this unit cell.

A: In a given unit cell, in addition to eight atoms at the eight corners of the unit cell, there is one…

Q: 5. Using curved-arrows, propose a mechanism for the following transformation and draw the major…

Q: 10. a) Provide the structures of reagent 1 and 2 that are required to generate the following alkyne:…

A: Here our Target compound is an internal alkyne . It can be obtained with the help of base followed…

Q: A brick has a mass of 4.0 kg and the Earth has a mass of 6.0 x 1027 g. Use this information to…

Q: If a scientist weighs out 460.69 grams of ethanol, what is the mass of the carbon dioxide? Make sure…

A: The given problem is a simple example of mole concept where, for a given balanced equation we have…

Q: НО Н Reducing одент я 1) NaBH in MeOH 2) H,O*

A: Sodium borohydride, NaBH4 is a reducing agent and it can selectively reduce a carbonyl functional…

Q: Using Table 10-2 of your textbook, assign chemical shift values to the proton or protons indicated…

A: Every nuclei will have spin and if an external magnetic field is applied, there will be an energy…

Q: Using reaction equations, explain how you would synthesize each of the following compounds from the…

A: The question is based on the concept of organic synthesis. we need to synthesize the product using…

Q: A 9.00 L tank at 12.8 C is filled with 3.68g of sulfur tetrafluoride gas and 8.53g of dinitrogen…

A: Given, Mass of sulfur tetrafluoride (SF4)= 3.68 g we know, molar mass of sulfur tetrafluoride…

Q: Convert 400. atm in kPa. Round answer to 3 significant

A: The conversion formulae are: 1 atm = 1.01325 bar 1 bar = 105 Pa 1 KPa = 103 Pa 1 bar = 102 KPa…

Q: can you draw the balanced equation for the formation of the [Ni(dmg)2] complex including the…

A: Ni2+ reacts with Hdmg or dimethylglyoxime and produces nickel bis(dimethylglyoximate) or Ni(dmg)2…

Q: Complete the diagram of reactions without mechanisms by giving the reaction conditions or the…

A: The question is based on organic reactions. we need to identify the product formed and explain…

Q: The reaction on the graph is: X+ BAXA+B Transition State A----B M Graph 1 Potential Energy X + A-B…

A: Displacement reaction: In these reaction an ion (or an atom) in a compound is by an ion ( or an atom…

Q: Provide the structure for the major product formed when the molecule drawn below is treated with…

A: 1. Ozonolysis of alkene 2. Anti-Markovnikoff addition of HBr to alkene 3. Addition of HCl to alkene…

Q: A chemist is preparing Aspirin (acetylsalicylic acid) using 100 g of salicylic acid and 100 g acetic…

Q: 14. Draw the major product(s) expected from each of the following reactions: * b) d) CF3 SO3H…

A: The given organic reactions are undergoes aromatic electrophilic substitution reactions.

Q: Properties of Solids CRYSTALLINE AMORPHOUS WO CER PRACTICE Summarize an explanation of your Review &…

A: We have two images from which one is crystalline solid and one is amorphous solid. We have to…

Q: 3. A solution of 3.6 g of NaOH (a strong base) is added to enough water to create a volume of 2.6 L…

Q: What are the fundamental factors that determine the rate of a chemical reaction and how do they…

A: Chemical reaction rates are influenced by various key factors that determine the speed at which…

Q: What mass of cesium bromide must be added to 0.500 L of water d=1.00 to produce a 0.650 m solution?…

A: We have to find the mass of cesium bromide that has to be added to 500 mL of water to form 0.650…

Q: Calculate the mass of camphor (C₁H₁O) that contains a billion (1.000 × 10⁹) carbon atoms. 16 Be sure…

A: Avogadro's Constant - 6.022 × 1023. The number of moles of any given compund can be calculated…

Q: According to the following reaction, how many grams of hydrobromic acid are needed to form 26.7…

A: Given, mass of bromine form = 26.7 g we know, molar mass of bromine(Br2) = 159.808 g/mol =>…

Q: Outline mechanism for the following reaction: PPh3 CH3. H

A: In this reaction,at first presence of pph3 there occurs nucleophilic attack occurs at the less…

Q: Which of these is not a possible product of the following reaction: OPP E₁ Possible Products E

A: For the given reaction, we have to have a product that will not form.

Q: Organic nitroxyls such as 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) are stable in solution and…

A: “Since you have posted a question with multiple sub-parts, we will solve the first three subparts…

Q: When 4.13 g of a certain molecular compound X are dissolved in 35. g of cyclohexane (C6H₁2), the…

Q: Decide whether each proposed multiplication or division of measurements is possible. If it is…

A: Introduction :- We can always multiply or divide measurements having same unit or different units.…

Q: Guided Practice Directions: Complete all problems. Ensure your work is shown, and proper units are…

Q: A mixture of gaseous reactants is put into a cylinder, where a chemical reaction turns them into…

A: Given : Heat flows into the system, Q = +227 KJ where positive sign indicates heat is added to the…

Q: How does the concept of aromaticity manifest in non-planar molecules, and how does it impact their…

A: The concept of aromaticity in chemistry refers to a special type of stability exhibited by certain…

Q: A suspension initially containing 200 mg of drug A was stored on a shelf at 20 °C for 60 days.…

A: For zero order reaction: At = Ao - Kt ( for reactants) Ao = Initial concentration of A At =…

Q: If 15.3 grams of chloriine react with 8.6 grams of calcium to form calcium chloride, what is the…

Q: A ferrous sulfate (BP) [FeSO4151.9g/mol] sample was analysed by titration using ammonium cerium (IV)…

A: The balanced chemical equation for the reaction is 3FeSO4 + 3(NH4)2Ce(NO3)6 → Fe2(SO4)3 + Fe(NO3)3…

Q: Identify the functional group(s) that appear in the molecule below. ооооооооооооооооооо Amine…

A: The properties of a molecule mainly depends upon an atom or group known as functional group.

Q: When 2,400 mg zinc is added to hydrochloric acid, 450 mL of hydrogen gas forms at a temperature of…

Q: ||| NAMING AND DRAWING ORGANIC MOLECULES Identifying organic functional groups compound H 1 CH3-C-…

Q: A gas occupies a volume of 5.3L at 30.2kPa. What volume will the gas occupy at 185.2kPa ? The…

A: According to Boyle's Law, for a fixed amount of gas at a constant temperature, the pressure and…

Q: Identify the diene and dienophile expected to produce the Diels-Alder product shown in the box…

A: Diels-Alder reaction involves the reaction of an electron-rich diene with an electron-deficient…

Q: 1. In an experiment, 8.75 g of aluminum reacts with 10.85g of iron(II) oxide FeO, to produce iron…

A: Weight of Al = 8.75 gm Weight of FeO = 10.85 gm

Q: Draw a resonance structure that places a pi bond in a different position. Include all lone pairs in…

Q: Ammonium phosphate ((NH), PO₂) is is an important ingredient in many solid fertilizers. It can be…

Q: Select the compound below that you would expect to have the higher boiling point. CH3(CH2)7CH3…

A: Hydrocarbons are non-polar in nature. In non-polar compounds, the interaction present in them is…

Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

I need help to find the mechansim for Preparation of Cyclohexanone by Na2CrO3/H2SO4 and explain the mechanisms

step by step so I can understand it please

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1: Given data

VIEW

Step 2: Explanations

VIEW

Solution

VIEW

Step by step

Solved in 3 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The following sequence of steps converts (R)-2-octanol to (S)-2-octanol. Propose structural formulas for intermediates A and B, specify the configuration of each, and account for the inversion of configuration in this sequence.
Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.
What would be a proposed mechanism to get from cyclohexanol to cis-2-methoxycyclohexanol? I know how to get from cyclohexanol to trans-2-methoxycyclohexanol would be to go through acid-catalyzed dehydration via H2SO4, then epoxide ring formation via mCPBA and then alcohol-catalyzed opening, but don't know how to do for the cis version, if possible.
: Treatment of (CHa)CHCH(OH)CH,CH3 with TSOH affords two products (M and N) with molecular formula CgH12. The 'H NMR spectra of M and N are given below. Propose structures for M and N and draw a mechanism to explain their formation. 1H NMR of M 3H 1H NMR of N 3H 3H 3 H 1H 3 H 2 H 2H 2H 8 7 6 4 1 0 9 8. 2 1 ppm ppm 4.
H₂C ཏཱཏི 1 ནི OH 1. Br2, PBг3 2. H₂O H3C OH Br The a-bromination of carbonyl compounds by Br2 in acetic acid is limited to aldehydes and ketones because acids, esters, and amides don't enolize to a sufficient extent. Carboxylic acids, however, can be a-brominated by first converting the carboxylic acid to an acid bromide by treatment with PBr3. Following enolization of the acid bromide, Br2 reacts in an a-substitution reaction. Hydrolysis of the acid bromide completes the reaction. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions :0: H3C Br Br + :::OH2 Br H₂O H3C Br за
3. The reaction of bromine with 3-hexanone produces two isomeric products of formula C6H11BrO. Give the mechanism for obtaining the two isomers.
Amantadine is effective in preventing infections caused by the influenza A virus and in treating established illnesses. It is thought to block a late stage in the assembly of the virus. Amantadine is synthesized by treating 1-bromoadamantane with acetonitrile in sulfuric acid to give N-adamantylacetamide, which is then converted to amantadine. CH,C=N in H,SO, Br NHCCH3 NH2 1-Bromoadamantane Amantadine (a) Propose a mechanism for the transformation in Step 1. (b) Describe experimental conditions to bring about Step 2.
How would the following conversion be achieved? Please show the reaction mechanism step by step
b) Refer to the following equation to answer Q3b (i), (ii) and (iii). CH3 H,SO, Н—с—он C-CH3 ? + H2O Но- ČH3 (i) Determine the product of the above reaction. (ii) Name the above reaction. (iii) Propose the mechanism for the above reaction.
Provide the reagent(s) and the reaction mechanism of the following reaction H₂N
Write four examples of the condensation reactions of carbonyl compounds, starting with benzaldehyde (C6H5CHO), with appropriate reagents and appropriate reactions. Write down the mechanism of one you want in detail.
[24166 Ji 10201900 (c) Propose reagents and conditions for the following 3-step synthesis of secondary amine 10, starting from azide 9. Your answer should include reagents and conditions for all three steps and a full curly arrow mechanism for the benzylation step (i.e. from primary amine 11 to secondary amine 12). Comment on any predicted selectivity. N3 m obydob is 10 br 9, 0-0 25 ilqmoxs of ozonit o = =Et Isaiavda se ni tons 3 steps Benzylation step: bre quotesmotional sies no H₂NY 11:0g 00S - (0=01 BOYH2OJA 0-3168 A3T23 ZI N H ZI H 12 10 wwww -Et