Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Hydrazine, N2H4, is a liquid substance used in rocket fuels. Its combustion liberates 622.4 kJ of
energy. For the reaction: N2H4(l) + O2(g) → N2(g) + 2 H2O (l) ∆H°rxn = -622.4 kJ
a. Calculate the ∆Hf of hydrazine.
b. The absolute entropy of hydrazine is 219.5 J/ K•mol, Use the standard
to calculate the ∆S° for the reaction.
c. Use the standard enthalpy and entropy of the reaction to calculate the ∆G°.
d. Use the values of ∆G° for the reaction to calculate the Gibb’s free energy of formation of
hydrazine.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution
Trending nowThis is a popular solution!
Step by stepSolved in 3 steps with 1 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemical-engineering and related others by exploring similar questions and additional content below.Similar questions
- Mn in groundwaterA ground water has the following conditions:{Mn2+ (aq)} = 1.0x10 -5pH = 7.0 (i.e., {H+ } = 1.0x10-7)Saturated with oxygen from the atmosphere: {O 2(aq)} = 2.63x10 -4T = 25 °C(a) Write the balanced equation for oxidation of reduced manganese,Mn2+ (aq), by dissolved oxygen (O 2(aq)) to generate MnO 2(s)(manganese dioxide) or MnOOH(s) (manganite), respectively.(b) Determine whether each of the above two reactions isthermodynamically favorable in the ground water. Which phase ofthe manganese oxide is more stable in the ground water?(c) If groundwater is at 5 oC, does oxidation of Mn 2+ (aq) by dissolvedoxygen to generate MnO 2(s) become more or less favorable?Calculate the saturated {Mn 2+ (aq)} assuming the water pH remainsat 7.0 and the dissolved oxygen concentration is 3.73x10 -4 M. 25C and 1 atm Please be as detailed as possible. I want to be able to replicate. Thank you so much. :)arrow_forwardA compound contains only carbon, hydrogen, nitrogen, and oxygen. Combustion of 0.157 g of the compound produced 0.213 g CO2 and 0.0310 g H2O. In another experiment, it is found that 0.103 g of the compound produces 0.0230 g NH3.What is the empirical formula of the compound? Hint: Combustion involves reacting with excess O2. Assume that all the carbon ends up in CO2 and all the hydrogen ends up in H2O. Also assume that all the nitrogen ends up in the NH3 in the second experiment.arrow_forward9.20. Ammonia is oxidized with air to form nitric oxide in the first step of the production of nitric acid. Two principal reactions occur: 4 NH3 + 5 024 NO + 6 H₂O 2 NH3 + 2O₂ → N₂ + 3 H₂O A flowchart of the reactor follows. 100 mol NH3(g)/min 25°C, 8 bar 900 mol air/min 0.21 02 0.79 N₂ 150°C, 8 bar REACTOR Product gas: 700°C, 8 bar 90 mol NO/min 0000 150 mol H₂O(v)/min 716 mol N₂/min 69 mol 0₂/min ġ(kJ/min)arrow_forward
- Liquid octane (C8H18) at 25°C, 1 atm enters a combustion chamber operating at steady state and burns completely with 50% excess air entering at 77°C, 1 atm. The products exit at 727°C, 1 atm. Determine the rate of heat transfer between the reactor and its surroundings, in kJ per kmol of fuel. Ignore kinetic and potential energy effects.arrow_forwardX Your answer is incorrect. Liquid ethanol (CH;OH) at 25°C, 1 atm enters an insulated reactor operating at steady state and burns completely with air entering at 370 K, 1 atm. The combustion products exit at 1300 K. Kinetic and potential energy effects can be neglected and the air can be modeled as 21% O, and 79% N2 on a molar basis. Determine the percent excess air used. 51arrow_forwardH1.arrow_forward
- Q3. The heat of combustion of methane, carbon monoxide and hydrogen are P, Qand R respectively. For the reaction below, CH4 +H20→CO+3H2 the heat of reaction is given by (A) P-Q-3R (B) Q+3R-P (C) P-Q-R (D) Q+R-Parrow_forwardJ 5arrow_forward. CO₂ entering from a combustion (T = 500°C) process is mixed stoichiometrically with H₂ at (T= 25°C). A reaction occurs over a catalyst producing water and methane with a 70% conversion of the reactants. If the products leaving the reactor have a temperature of 725°C calculate the heat transfer to or from the reactor. CO₂ + 4H₂ → 2H₂O+CHA Assume Constant Cp for all components except H₂O. kJ mole. C CO2: Cp= 0.037 kJ mole C CO₂ T = 500°C H₂ T = 25°C H2: Cp = 0.029. Reactor kJ mole. C CH4: Cp = 0.033- CO2, H2, H₂O, CH4 T = 725°Carrow_forward
- The normal boiling temperature of benzene is 353.24 K, and the vapor pressure of liquid benzene is 1.19 X 104 Pa at 20.0°C. The enthalpy of fusion is 9.95 kJ mol-¹, and the vapor pressure of solid benzene is 137 Pa at -44.3°C. Calculate the following: a. AH vaporization b. AS vaporization c. Triple point temperature and pressurearrow_forwardRegarding the following reaction, A (s) + 2B (g) →→ C (1) + 3D (g) ArH(298K)=91.4kJ/mol where g, I, s - means gas, liquid and solid, respectively, and assuming all gases are perfect gas, calculate ArU(298K). Instruction: Please enter your answer (unit:kJ/mole) round to 2 decimal place.arrow_forwardTopic: Introduction to Chemical Engineering Thermodynamicsarrow_forward
arrow_back_ios
arrow_forward_ios
Recommended textbooks for you
- Introduction to Chemical Engineering Thermodynami...Chemical EngineeringISBN:9781259696527Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark SwihartPublisher:McGraw-Hill EducationElementary Principles of Chemical Processes, Bind...Chemical EngineeringISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEYElements of Chemical Reaction Engineering (5th Ed...Chemical EngineeringISBN:9780133887518Author:H. Scott FoglerPublisher:Prentice Hall
- Industrial Plastics: Theory and ApplicationsChemical EngineeringISBN:9781285061238Author:Lokensgard, ErikPublisher:Delmar Cengage LearningUnit Operations of Chemical EngineeringChemical EngineeringISBN:9780072848236Author:Warren McCabe, Julian C. Smith, Peter HarriottPublisher:McGraw-Hill Companies, The
Introduction to Chemical Engineering Thermodynami...
Chemical Engineering
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind...
Chemical Engineering
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY
Elements of Chemical Reaction Engineering (5th Ed...
Chemical Engineering
ISBN:9780133887518
Author:H. Scott Fogler
Publisher:Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:9781285061238
Author:Lokensgard, Erik
Publisher:Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:9780072848236
Author:Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:McGraw-Hill Companies, The