How would you interpret this IR spectra of fluorene? What I mean by this is which peaks let you know its fluorene and which peaks show impurities if any such as 9-fluorenone since this lab required a separation of fluorene and 9-fluorenone. Other impurities could be solid alumina and sand and the solvents of pet. ether and dichlormethane.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter32: Gas Chromatography
Section: Chapter Questions
Problem 32.22QAP
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How would you interpret this IR spectra of fluorene? What I mean by this is which peaks let you know its fluorene and which peaks show impurities if any such as 9-fluorenone since this lab required a separation of fluorene and 9-fluorenone. Other impurities could be solid alumina and sand and the solvents of pet. ether and dichlormethane.

%T
100
100-
%T
75-
50-
25-
0
4000
4000
3000
3061.03-
2916.37-
3000
2000
2000
LabSolutions Lab SolutionsIR¥Data CHEM
23 Spring 2023 MW Dhimitruka¥AR and GJ -
Vhite.ispd
2
3
1500
Item
Sample name
Sample ID
Option
5 Intensity Mode
6
4
1500
Apodization
No. of Scans
9
10 Resolution
1000
AR and GJ - White
734.881
734.88
596.30
623.01
472.56
1000
408.91
16
4 cm-1
500
cm-1
389.62
370.33
347.19
356.83
500
cm-1
Value
%Transmittance
Happ-Genzel
696.30
1090.30
Corr.
Intensity
9.90
12.99
6.59
2.74
9.13
1.64
2.65
4.29
14.29
Peak
1
88.42
347.19
2 356.83 84.72
3 370.33 88.87
4 389.62 89.99
408.91
472.56
69.99
84.68
5
6
1472.00
7
623.01
8
0
9
734.88
734.00
72.28
123 11
12.20
10
72.28
23.11
23.11
1.18
2.56
3.28
117
1.17
13
14
15
16
40
3.10
74
734.88
11
862.18
94.40
12 952.84 93.18
999.13 92.75
1107.14 94.08
1190.08 92.01
1234.44 94.61 0.71
17 1309.67 92.89 2.18
18 1402.25 92.27 1.68
19 1446.61 86.47 9.20
20 1967.39 93.89 0.04
21 2173.78 93.51 0.08
22 2357.01 93.37 0.31
23 2916.37 92.69 0.89
24 3061.03
92.66
0.73
Intensity
93.50
93.42
09:44
90.36
SHIMADZU
Corr.
Area
Area
33.492
Base (H) Base (L)
349.12
27.067
343.33
360.69 352.97 69.282 51.635
376.12 366.48 82.043 35.193
391.55 381.91 81.002 18.412
420.48 403.12 171.108 67.211
466.77 64.538
478.35
8.256
626 87 607.58 92.455 14.960
1704.02
187.688
673.16
30.342
759.95 704.02 649.425 386.449
1704.02
759.95
649.425 386.449
869.90 850.61 92.765 6.067
8.087
962.48
943 19 99.153 16.970
1004.91
1112.93
4407 70
10.970
983.70
1097.50
111.095
80.236
1165.00 196.532
23.658
6.677
35.462
4.333
1197.79
1240.23 1224.80 76.665
1317.38 1303.88 78.402 12.583
1415.75 1388.75 185.860
1460.11 1421.54 291.909
22.499
112.199
0.314
0.788
1969.32 1957.75 69.893
2185.35 2171.85 85.777
2360.87 2347.37 85.719 2.097
2945.30 2887.44 387.647 16.245
3076.46 3049.46 184.368 7.290
Comment
Transcribed Image Text:%T 100 100- %T 75- 50- 25- 0 4000 4000 3000 3061.03- 2916.37- 3000 2000 2000 LabSolutions Lab SolutionsIR¥Data CHEM 23 Spring 2023 MW Dhimitruka¥AR and GJ - Vhite.ispd 2 3 1500 Item Sample name Sample ID Option 5 Intensity Mode 6 4 1500 Apodization No. of Scans 9 10 Resolution 1000 AR and GJ - White 734.881 734.88 596.30 623.01 472.56 1000 408.91 16 4 cm-1 500 cm-1 389.62 370.33 347.19 356.83 500 cm-1 Value %Transmittance Happ-Genzel 696.30 1090.30 Corr. Intensity 9.90 12.99 6.59 2.74 9.13 1.64 2.65 4.29 14.29 Peak 1 88.42 347.19 2 356.83 84.72 3 370.33 88.87 4 389.62 89.99 408.91 472.56 69.99 84.68 5 6 1472.00 7 623.01 8 0 9 734.88 734.00 72.28 123 11 12.20 10 72.28 23.11 23.11 1.18 2.56 3.28 117 1.17 13 14 15 16 40 3.10 74 734.88 11 862.18 94.40 12 952.84 93.18 999.13 92.75 1107.14 94.08 1190.08 92.01 1234.44 94.61 0.71 17 1309.67 92.89 2.18 18 1402.25 92.27 1.68 19 1446.61 86.47 9.20 20 1967.39 93.89 0.04 21 2173.78 93.51 0.08 22 2357.01 93.37 0.31 23 2916.37 92.69 0.89 24 3061.03 92.66 0.73 Intensity 93.50 93.42 09:44 90.36 SHIMADZU Corr. Area Area 33.492 Base (H) Base (L) 349.12 27.067 343.33 360.69 352.97 69.282 51.635 376.12 366.48 82.043 35.193 391.55 381.91 81.002 18.412 420.48 403.12 171.108 67.211 466.77 64.538 478.35 8.256 626 87 607.58 92.455 14.960 1704.02 187.688 673.16 30.342 759.95 704.02 649.425 386.449 1704.02 759.95 649.425 386.449 869.90 850.61 92.765 6.067 8.087 962.48 943 19 99.153 16.970 1004.91 1112.93 4407 70 10.970 983.70 1097.50 111.095 80.236 1165.00 196.532 23.658 6.677 35.462 4.333 1197.79 1240.23 1224.80 76.665 1317.38 1303.88 78.402 12.583 1415.75 1388.75 185.860 1460.11 1421.54 291.909 22.499 112.199 0.314 0.788 1969.32 1957.75 69.893 2185.35 2171.85 85.777 2360.87 2347.37 85.719 2.097 2945.30 2887.44 387.647 16.245 3076.46 3049.46 184.368 7.290 Comment
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