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Science
Chemistry
How could you prepare 3,3-di bromo hexane from reagent from contain only 2 carbons
How could you prepare 3,3-di bromo hexane from reagent from contain only 2 carbons
BUY
Organic Chemistry
9th Edition
ISBN:
9781305080485
Author: John E. McMurry
Publisher:
Cengage Learning
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1 Structure And Bonding
2 Polar Covalent Bonds; Acids And Bases
3 Organic Compounds: Alkanes And Their Stereochemistry
4 Organic Compounds: Cycloalkanes And Their Stereochemistry
5 Stereochemistry At Tetrahedral Centers
6 An Overview Of Organic Reactions
7 Alkenes: Structure And Reactivity
8 Alkenes: Reactions And Synthesis
9 Alkynes: An Introduction To Organic Synthesis
10 Organohalides
11 Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations
12 Structure Determination: Mass Spectrometry And Infrared Spectroscopy
13 Structure Determination: Nuclear Magnetic Resonance Spectroscopy
14 Conjugated Compounds And Ultraviolet Spectroscopy
15 Benzene And Aromaticity
16 Chemistry Of Benzene: Electrophilic Aromatic Substitution
17 Alcohols And Phenols
18 Ethers And Epoxides; Thiols And Sulfides
19 Aldehydes And Ketones: Nucleophilic Addition Reactions
20 Carboxylic Acids And Nitriles
21 Carboxylic Acid Derivatives: Nucleophilic Acyl Substitution Reactions
22 Carbonyl Alpha-substitution Reactions
23 Carbonyl Condensation Reactions
24 Amines And Heterocycles
25 Biomolecules: Carbohydrates
26 Biomolecules: Amino Acids, Peptides, And Proteins
27 Biomolecules: Lipids
28 Biomolecules: Nucleic Acids
29 The Organic Chemistry Of Metabolic Pathways
30 Orbitals And Organic Chemistry: Pericyclic Reactions
31 Synthetic Polymers
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18.1 Names And Properties Of Ethers
18.2 Preparing Ethers
18.3 Reactions Of Ethers: Acidic Cleavage
18.4 Reactions Of Ethers: Claisen Rearrangement
18.5 Cyclic Ethers: Epoxides
18.6 Reactions Of Epoxides: Ring-opening
18.7 Crown Ethers
18.8 Thiols And Sulfides
18.9 Spectroscopy Of Ethers
18.SE Something Extra
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Problem 19VC: Give IUPAC names for the following compounds (reddish brown = Br; yellow = S):
Problem 20VC: Show the product, including stereochemistry, that would result from reaction of the following...
Problem 21VC
Problem 22VC: Treatment of the following alkene with a peroxyacid yields an epoxide different from that obtained...
Problem 23MP
Problem 24MP
Problem 25MP: Predict the product(s) and provide the mechanism for each two-step process below.
Problem 26MP: The alkoxymercuration of alkenes involves the formation of an organomercury intermediate (I), which...
Problem 27MP: Predict the product(s) and provide the mechanism for each reaction below. What do the mechanisms...
Problem 28MP: Predict the product(s) and provide the mechanism for each reaction below. What do the mechanisms...
Problem 29MP
Problem 30MP: Ethers undergo an acid-catalyzed cleavage reaction when treated with the Lewis acid BBr3 at room...
Problem 31MP: Treatment of 1, 1-diphenyl-l, 2-epoxyethane with aqueous acid yields diphenylacetaldehyde as the...
Problem 32MP: Fluoxetine, a heavily prescribed antidepressant marketed under the name Prozac, can be prepared by a...
Problem 33MP: When 2-methyl-2, 5-pentanediol is treated with sulfuric acid, dehydration occurs and 2,...
Problem 34MP
Problem 35MP
Problem 36MP: Aldehydes and ketones undergo acid-catalyzed reaction with alcohols to yield hemiacetals, compounds...
Problem 37MP: Propose a mechanism to account for the following transformation. What two kinds of reactions are...
Problem 38AP
Problem 39AP
Problem 40AP: How would you prepare the following ethers?
Problem 41AP
Problem 42AP: tert-Butyl ethers can be prepared by the reaction of an alcohol with 2-methylpropene in the presence...
Problem 43AP: Treatment of trans-2-chlorocyclohexanol with NaOH yields 1, 2-epoxy- cyclohexane, but reaction of...
Problem 44AP: Predict the products of the following ether cleavage reactions:
Problem 45AP
Problem 46AP
Problem 47AP: Write the mechanism of the hydrolysis of cis-5, 6-epoxydecane by reaction with aqueous acid. What is...
Problem 48AP
Problem 49AP: Acid-catalyzed hydrolysis of a 1, 2-epoxycyclohexane produces a transdiaxial 1, 2-diol. What product...
Problem 50AP
Problem 51AP: Epoxides are reduced by treatment with lithium aluminum hydride to yield alcohols. Propose a...
Problem 52AP
Problem 53AP: The red fox (Vulpes vulpes) uses a chemical communication system based on scent marks in urine. One...
Problem 54AP: Anethole, C10H12O, a major constituent of the oil of anise, has the 1H NMR spectrum shown. On...
Problem 55AP: Propose structures for compounds that have the following 1H NMR spectra: (a) C5H12S (An -SH proton...
Problem 56GP
Problem 57GP: How would you synthesize anethole (Problem 18-54) from phenol?
Problem 58GP: How could you prepare benzyl phenyl ether from benzene and phenol? More than one step is required.
Problem 59GP: Meerwein's reagent, triethyloxonium tetrafluoroborate, is a powerful ethylating agent that converts...
Problem 60GP
Problem 61GP
Problem 62GP: The Zeisel method is an old analytical procedure for determining the number of methoxyl groups in a...
Problem 63GP
Problem 64GP
Problem 65GP
Problem 66GP: Identify the reagents a-e in the following scheme:
Problem 67GP: Propose structures for compounds that have the following 1H NMR spectra:
Problem 68GP
Problem 69GP
Problem 70GP: Predict the product(s) if the starting materials below underwent a Claisen rearrangement. Draw...
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