HO Br ?? HO 0 OH A 1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. Hg(OAc)2/H2O b. NaBH4; 6. TBAF B 1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. BH3 b. H202, NaOH: 6. TBAF 1. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. BH3 b. H2O2, NaOH O 1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me: 3. NaOMe/MeOH; 4. a. BH3 b. H2O2, NaOH; 5. TBAF

Chemistry
10th Edition
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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HO
Br
??
HO
0
OH
A
1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. Hg(OAc)2/H2O b.
NaBH4; 6. TBAF
B
1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. BH3 b. H202,
NaOH: 6. TBAF
1. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. BH3 b. H2O2, NaOH
O 1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me: 3. NaOMe/MeOH; 4. a. BH3 b. H2O2, NaOH; 5. TBAF
Transcribed Image Text:HO Br ?? HO 0 OH A 1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. Hg(OAc)2/H2O b. NaBH4; 6. TBAF B 1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. BH3 b. H202, NaOH: 6. TBAF 1. a, Mg(0) b. Me(CO)Me; 3. Ts-CI/Pyridine; 4. NaOMe/MeOH; 5. a. BH3 b. H2O2, NaOH O 1. TMS-CI/Triethylamine; 2. a, Mg(0) b. Me(CO)Me: 3. NaOMe/MeOH; 4. a. BH3 b. H2O2, NaOH; 5. TBAF
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