
Chemistry
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ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Transcribed Image Text:What is the rate constant of a first-order reaction if the half-life is 6.14
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- The rate for the reaction H2 (g) + Br2 (g) 2 HBr (g)is first order in both H2 and Br2 concentrations, and the rate constant k at 287 \deg C is 5.87\times 10-4 L mol-1 s-1. Suppose 1.00 L of H2 (g) at a concentration of 6.60\times 10-2 M is rapidly mixed with the same volume of Br2 (g) also at a concentration of 6.60\times 10-2 M. Calculate the time (in seconds) required for the H2 concentration to decrease to a value of 2.55\times 10-2 M. (Enter your answer to three significant figures.)arrow_forward39. The decomposition of a certain pesticide was found to follow first-order kinetics. A student finds that after 3.0 months a sample of pesticide was 87.5% decomposed (only 12.5% of the pesticide remained). What is the half-life (112) for the decomposition reaction? a. 1.0 months b. 2.0 months 3.0 months d. The half-life can not be determined with the information provided.arrow_forwardThe rate constant k, for the reaction described below is 4.53 x 10-3 M 1s 1 C,HĄB12 (aq) + 31 (aq) → C2H4 (g) + 2 Br (aq) + I3 (aq) rate = k[C2H4B12][I ] Based on the information provided above, determine the missing information in the table below. Run [C2H4B12]o (M) [I ]o (M) Initial Rate of C2H4 formation (M) 1 0.175 0.00210 2 0.300 0.000450 3 0.250 0.350 a) b) c)arrow_forward
- Give the characteristic of a first order reaction having only one reactant. The rate of the reaction is not proportional to the concentration of the reactant. The rate of the reaction is proportional to the square of the concentration of the reactant. The rate of the reaction is proportional to the square root of the concentration of the reactant. The rate of the reaction is proportional to the natural logarithm of the concentration of the reactant. The rate of the reaction is directly proportional to the concentration of the reactant.arrow_forward1. Sucrose (C12H22011) inversion is the process by which the substance is converted into either glucose or fructose (both have the formula CoH12O6). The process results in optical inversion (mirror image of structures), The reaction follows a first-order kinetics with a rate constant of 3.6 X 103 /s. C12H22011(aq) + H20(1) → 2C6H12Oglaq) a) If a 0.15 M C6H1206 solution would undergo inversion at 25°C, what is its concentration after 2.0 minutes? b) What is the half-life of the reaction?arrow_forwardIbuprofen is an over the counter medicine used to alleviate pain. The metabolism of ibuprofen in the body follows first-order kinetics. For ibuprofen to be effective, the concentration within the body’s blood must stay above 5.3x10-5 M. A typical dose of ibuprofen is around 600 mg, which gives a concentration of 6.5x10-4 M. How long, in hours, will it take for a dose of 600 mg to reach the point where the ibuprofen is no longer effective? The rate constant for the metabolism of Ibuprofen if 0.0104 1/M min.arrow_forward
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