Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A chemist designs a galvanic cell that uses these two half-reactions: half-reaction standard reduction potential Br,(1)+2e 2 Br (aq) :+1.065 V (red Cro, (aq)+4 H,O(1)+3e Cr(OH)3(s)+5 OH (aq) -0.13 V (red Answer the following questions about this cell. Write a balanced equation for the half-reaction that happens at the cathode. x10 Write a balanced equation for the half-reaction that happens at the anode.arrow_forwardA student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AGO. . • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions E. His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 2. cell n A B U 2 2 2 calculated quantities (Check the box next to any that are wrong.) AGⓇ 64, kJ/mol O -160, kJ/mol -228. kJ/mol O O K -12 6.13 X 10 O -29 9.32 × 10 O 1.14 X 10 40 O 0 E 0.33 V 0.83 V 1.18 V O O G oarrow_forwardA student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG". • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions E. His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. calculated quantities (Check the box next to any that are wrong.) cell n 46° K 1 - 124. kJ/mol 5.30 x 10 21 -1.28 V -18 4.53 x 10 B 1 - 99. kJ/mol -1.03 V -7 2.20 x 10 1 - 38. kJ/mol 0.39 Varrow_forward
- Sometimes in a galvanic cell, an inert electrode is needed. What element is typically used? (Give the symbol)arrow_forwardConsider the following galvanic cells. Diagram I Au- 1.0 M Au³+ chemPad XX 80 1.16 80 (b) balanced cell equation II chemPad X V For each galvanic cell, give the balanced cell reaction and determine &. Standard reduction potentials are found in the Standard Reduction Potentials table. (Use the lowest possible whole number coefficients. Include states-of-matter under the given conditions in your answer.) (a) balanced cell equation I 1.4 1.0 M Cu+ 1.0 M Cu²+ Au(s)+3Cu²+(aq) ⇒ Au³+(aq)+3Cu+(aq) |Au(s)+3Cu^2+(aq)Au^3+(aq)+3Cu^+(aq) Your answer indicates a reaction progressing in an inconsistent direction. -Pt Greek V i Diagram II Greek Cd- 1.0 M Cd2+ XX Enter a number. Cd(s)+2VO₂²+ (aq)+4H*(aq) ← Cd²+(aq)+2VO²+ (aq)+2H₂O(l) Cd(s)+2VO_2^2+(aq)+4H^+(aq)<--Cd^2+(aq)+2VO^2+(aq)+2H_2O(l) Your answer indicates a reaction progressing in an inconsistent direction. Help Help -Pt 1.0 M VO₂ 1.0 MH+ 1.0 M VO²+ iarrow_forwardA student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AGº. • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions E". His results are listed below. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if any. Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. calculated quantities (Check the box next to any that are wrong.) cell n aG K E -21 1.42 x 10 A 1 119. kJ/mol O 1.23 V -- В - 51. kJ/mol 1.16 X 10 -0.53 V -11 2.06 X 10 1 -61. kJ/mol 0.63 Varrow_forward
- bew DARGERS Determine the thermodynamic equilibrium constant K for a voltaic cell made of a Ag strip and an Al strip immersed in 1.0 M aqueous AgNO3 and Al(NO3)3 solutions, respectively, at 25.00°C, with all other cell components in place. (Use Table 18.3 for your standard cell potentials.) Type your numeric answer and submit Hint Equation 18.8 in Section 18.3.1 relates cell voltage to AG. SOPINIOANE Cat 0 Cannot be empty HE HIG Xarrow_forwardA student made measurements on some electrochemical cells and calculated three quantities: • The standard reaction free energy AG⁰. • The equilibrium constant K at 25.0 °C. • The cell potential under standard conditions º His results are listed below. any. Unfortunately, the student may have made some mistakes. Examine his results carefully and tick the box next to the incorrect quantity in each row, if Note: If there is a mistake in a row, only one of the three quantities listed is wrong. Also, you may assume the number of significant digits in each quantity is correct. Also note: for each cell, the number n of electrons transferred per redox reaction is 1. cell n A B C 1 calculated quantities (Check the box next to any that are wrong.) AGⓇ 37. kJ/mol - 66. kJ/mol -47. kJ/mol K 6 3.03 × 10 2.74 × 10 5.83 × 10 12 9 X 0 E -0.38 V 0.68 V -0.49 V Sarrow_forward
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