Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Galvanic cells are composed of non-spontaneous
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- 4 A certain metal M forms a soluble sulfate salt MSO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 1.50 M solution of MSO and the right half cell with a 75.0 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 40.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left right x10 X Śarrow_forwardWhat is the Eθ cell value for a galvanic cell constructed using aluminium and nickel electrodes.arrow_forwardA Galvanic cell consists of Mg electrode in a 1.0 mol L -1 Mg(NO3)2 solution and a Ag electrode in a 1.0 mol L-1 AgNO3 solution. Calculate standard emf for the spontaneous reaction of this electrochemical cell at 25 Carrow_forward
- A certain metal M forms a soluble sulfate salt MSO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 125. mM solution of MSO4 and the right half cell with a 2.50 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 40.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. left right x10 X Śarrow_forwardA certain metal M forms a soluble sulfate salt MSO4. Suppose the left half cell of a galvanic cell apparatus is filled with a 2.50 M solution of MSO, and the right half cell with a 25.0 mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 40.0 °C. left Which electrode will be positive? x10 O right What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. necessary, and round it to 2 significant Be sure your answer has a unit symbol, digits.arrow_forwardPlease show solutions and answer. Thank you !arrow_forward
- Please don't provide handwritten solutionarrow_forwardCalculate the standard cell potential and note whether the reaction is spontaneous under standard conditions. Mg(s) + Cu2+ --> Mg2+ + Cu(s)arrow_forwardA certain metal è forms a soluble sulfate salt ₂(so). Suppose the left half cell of a galvanic cell apparatus is filled with a 5.00 M solution of M₂(SO4)3 and the right half cell with a 250. mM solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 35.0 °C. Which electrode will be positive? O left Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. O right What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. 0 x10 Xarrow_forward
- = A certain half-reaction has a standard reduction potential Ered +1.24 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 1.00 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. 0 O yes, there is a minimum. red Ono minimum Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. O yes, there is a maximum. no maximum 0 E = v red By using the information…arrow_forwardQuestions 20 and 21 refer to the following information. Galvanic Cell Cell Diagram E°cell (Volts) Mg | Mg2(1.0 M) || Pb*2(1.0 M) | Pb 1 2.24 Zn | Zn(1.0 M) || Pb*2(1.0 M) | Pb 2 0.63 Mg | Mg*(1.0 M) || Zn*2(1.0 M) | Zn 3 The chemical reaction occurring in first galvanic cell is: Mg + Pb*2 → Mg+2 + Pb 21. If the concentration of Mg+2 is changed from 1.0 M to 3.0 M in the galvanic cells above, what will happen to the observed cell voltages in galvanic cells 1 and 3? (A) The voltage in both galvanic cells 1 and 3 will increase. (B) The voltage will decrease in both galvanic cells 1 and 3. (C) The voltage in galvanic cell 1 will increase and will decrease in galvanic cell 3 (D) The voltage in galvanic cell 3 will increase and will decrease in galvanic cell 1. 22. Consider a voltaic cell based on these half-cells. Ag (aq) +e → Ag/s) Cd (aq) + 2e → Cd¢s) E* = +0.80 V E = -0.40 V Identify the anode and give the voltage of this cell under standard conditions. (A) Ag; Ecell = 0.40 V (B) Ag;…arrow_forwardA certain metal M forms a soluble nitrate salt MNO3. Suppose the left half cell of a galvanic cell apparatus is filled with a 15.0 mM solution of MNO3 and the right half cell with a 3.00 M solution of the same substance. Electrodes made of M are dipped into both solutions and a voltmeter is connected between them. The temperature of the apparatus is held constant at 30.0 °C. Which electrode will be positive? What voltage will the voltmeter show? Assume its positive lead is connected to the positive electrode. Be sure your answer has a unit symbol, if necessary, and round it to 2 significant digits. O left 0 right x10 Xarrow_forward
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