Functional Group Transformations? Starting Compound Typical Reagents Compound and Reaction Class Class Conditions Formed HX HX (2 equiv) (5) -C C- -C-C- Alkyne HX Geminal dihalide H. H20 (6) -C=C- H-C-C TFOH, Alkyne CF3CH,OH Ketone
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Q: 1. Starting from 1-bromoethane, synthesize ethanenitrile Br CH3CEN 1-bromoethane ethanenitrile
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- Naming Alkenes 7-37 Name the following alkenes: (a) CH3 (b) CH3 CH2CH3 (c) CH2CH3 CH3CHCH2CH,CH CH3 H2C=CCH2CH3 CHCH2CH3 C=C H C=C H3C H3C H. H (f) H2C=C=CHCH3 (е) CH3 C=C (d) H H3C C=C CH3 C=C CH3 H3C H. H2C=CHCHCH CH3CH2CH2 CH36. The product(s) of the following reaction dd blow di CH2-CH2 excess HBr is/are: CH2 CH2 heat Od Al () (A od Ocf D (CHPPCOK (CHPCON G)D CH;CH2OCH,CH3 HO CH;CH,CH,CH,OH and CH;CH,CH2CH,Br II H t mol boumol toubong soinm od o CH2-CHBR HO CH2 CH2 BrCH-CH,CH-Cн,ОН and BrCH,CH,CH-CH,Br CityCHCH COM III IV A) I B) П O II D) IV E) None of these HO CH CH'OH6-46 Show how each compound might be synthesized by the SN2 displacement of an alkyl halide. SCH,CH, (a) -CH₂OH (c) (d) CHÍNH, 6-47 (a) Give twn synthecac fox (CI) qu (b) (e) H₂C=CH-CH₂CN n OLL BU (1) H-C=C-CH₂CH₂CH₂
- The following carbocation is an intermediate in the electrophilic addition reaction of HCl with two different alkenes. Identify both, and tell which C-H bonds in the carbocation are aligned for hyperconjugation with the vacant p orbital on the positively charged carbon.Naming Alkenes 7-37 Name the following alkenes: (а) CH3 (b) CH3 CH2CH3 (с) CH2CH3 CH3CHCH,CH,CH C=C H3C H CHCH2CH3 CH3 H2C=CCH2CH3 H H. (d) H CH3 (e) H. (f) H2C=C=CHCH3 H3C C=C c=c H3C =c CH,CH,CH2 H2C=CHCHCH H. CH3 CH3 CH3Br LiCu(CH3)2 6 (1) LiAlH4 2 3 Ahol follow (2) H₂O 0 Aci HBr (xs) H (2) H₂O+ -Li
- 2 Write the IUPAC name for each compound. Ο COC-M (a) HV Ο 0 || (d) H₂N- C (b) CH₂(CH₂),COCH, OTT HO noitos2) alodo d diw sobirbydaA to noilo ono evig of alcools dikw 39891 abitbydA (8.81 (c) CH₂(CH₂)4CNHCH, no bae totes me to slom 0 O CNH₂ با нио но но но HOOH + HOOO HO HOOOH OHO.HOOD HO || (e) CH₂CO-A iw sobixbydnA to noltoso. driw do A (D681 moitoo@) aoniMA "I w bn shomme a onions to solomeowths of elom ono bas shima Joubo aviy oj vig OH OHO bertiup bios biydisororesidenten (f) CH3CHCH₂COCH₂CH3Write the structures of Kand L, show exactly what happens in each reaction. Cycloocta triene 80-100°C cis,cis,cis-Cicloocta-1,3,5-trieno K (C;H10) COOCH3 A K + CH;00CC=CCOOCH, L (C,H1604) COOCH3 Ciclobuteno + Ftalato de dimetilo Ftalato de dimetilo dimethyl pht he laetePredict the product for the following reaction. H₂C A I and II HH3C xoxoxox B D IV E cis-1-bromo-3-methylcyclohexane ||| SH H₂C NASH III acetone Br H3C ||||SH IV H
- Q4 * 1,3-thiazolo[4,5,b]pyrdine 1,5-thiazolo[4,5,b]pyrdine 1,3-thiazol[4,5,c]pyridzine 6-thiabicyclo[4.5]decane 1-thia[5.6]decane Both are wrong Q5* ΟΟΟ Q6 * 2H-1,3-oxazete 4H-1,3-oxazete 2H-1,3-oxazane 4H-1,3-oxazane[17] H What is corect name of following? CH2CH3 HO CH3 Br 2R,35-2-brome. (2R,3S) 2-bromo-3-hydroxy pentane (2R,3R) 2-bromo-3-hydroxy pentane ((25,3S) 2-bromo-3-hydroxy pentane (01 اورا (S) 2-bromo-3-hydroxy pentane (2S,3R) 2-bromo-3-hydroxy pentane 3hr [18] Which of following compound will undergo solvolysis with methanol to yield the two shown? H3C OCH 3 CH3 CH3 OCH3 (a) (15,3S)-1-bromo-1,3-dimethyl-cyclohexane (b) (1R,3R)-1-bromo-1,3-dimethyl-cyclohexane (c) (15,3R)-1-bromo-1,3-dimethyl-cyclohexane (4) (1R)-1-bromo-1,3-dimethyl-cyclohexane (e) (15)-1-bromo-1,3-dimethyl-cyclohexaneAnswer the following questions related to the molecules whose structures are shown below. B A Q H H H H H H H H H H H I I II TIIITT Но-с-с-с-с-с-с-с-с-с-с-с-с-н CH;(CH2)14-Č–O–CH–(CH2)28-CH3 H H H H H H H H H HH Q H H H H H I I I T но -с-с-с-с-с с D H H H H HC-oo HC-O Hc-o E HC-O HC-O H,NH,CH,CO--0-CH2 Place A. B, D, and E in the order of least soluble in water to most soluble in water. B>D>A>E OA. B>A>D>E OB. A>B>D>E Oc E>D>B>A OD. A>D>B>E ---c-H H H H