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Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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For the two complex ions [Mn(CN)6]4− and [Mn(H2O)6]2+
(a) Are all metal ligand bonds equal to each other? Please explain taking into account the effects of Jahn-Teller distortion.
(b) Draw molecular orbital energy diagrams.
(Mn:25)
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- Identify each of the following pairs of coordination compounds as coordination isomers, linkage isomers, or geometric isomers. (a) [Cr(H2O)5(NO2)]Cl2 and [Cr(H2O)5(ONO)]Cl2(b) [Co(NH3)4Cl2]NO2 and [Co(NH3)4(NO2)2]Cl(c) [Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4](d) cis-[Co(NH3)4Cl2]Cl and trans-[Co(NH3)4Cl2]Cl(e) [Fe(H2O)5(SCN)](NO3)2 and [Fe(H2O)5(NCS)](NO3)2arrow_forward1) Is it possible to have isomers of the following coordination compounds? If this is the case, indicate the type of isomerism they present: [CoBrClI(OH2)] (tetrahedral) [Fe(CN)2(CH3NC)4]arrow_forwardSketch the following complexes. If more than one enantiomer exists, sketch just one.(a) mer-Cr(NH3)3(Cl)3 (b) cis-[Fe(H2O)4(CN)2]Cl (c) trans-[Ni(en)2Cl2] (d) fac-Co(NH3)3(CN)3arrow_forward
- Use your knowledge of electronic transitions in coordination compounds to justify why the compound [Fe(H2O)6]3+ is white in color. You can justify your answer supported by some scheme.arrow_forward5. What is the oxidation state of cobalt in [Co(NH3)3(OH2)2CI]Cl₂?arrow_forwardSC B. The Lewis diagram for NO₂ is: |:8_N_ő:] :0 N= Recall that for predicting geometry, double and triple bonds count as only one electron pair. The electron-pair geometry around the N atom in NO₂ is There are 1 ! Q A :6: F1 @ 2 W S -8 F2 # 3 lone pair(s) around the central atom, so the geometry of NO₂ is E 20 F3 D $ 4 F4 R F LL olo LO % 5 F5 T MacBook Pro < 6 G F6 Y & 7 Ja F7 H * U DII F8 8 00 Jarrow_forward
- 5. (a) (b) The complex ion NiC14² has two unpaired electrons, whereas Ni(CN)4² is diamagnetic. Propose structures for these two complex ions (square-planar or tetrahedral). Draw the crystal field diagrams of two complex ions.arrow_forwardPlease answer 22b c both.arrow_forwardYou have a solution of the following ion: [Fe(H2O)6]3+ a) Is the ion more likely paramagnetic or diamagnetic? Please explain. b) Predict how the crystal field splitting would change (increase or decrease) if all H2O ligands were replaced by NO2- in your solution. c) What is the general color of your original solution and how would the color change in part “b”?arrow_forward
- What is the charge on each of the following complex ions? hexaaquairon(II), [Fe(H2O)6]? tris(carbonato)ferrate(III), [Fe(CO3)3]? diaquatetrachlorovanadate(III), [V(H2O)2Cl4]? Express the charges numerically, in the order that the complexes are listed, separated by commas. For a nonzero charge, be sure to include the sign (e.g., +1,-2,+3).arrow_forwardBe sure to answer all parts. Complete the following statements for the complex ion [Co(en)2(H2O)CN]2+. (a) en is the abbreviation for (b) The oxidation number of Co is (c) The coordination number of Co is (d) is a bidentate ligand. (en) Co(en)2 CN H2Oarrow_forward[Fe(OH₂)6]²+ is paramagnetic whereas [Fe(CN)6]4 is diamagnetic. Which of the following provides the best explanation for this? As a weak field ligand, H₂O induces a larger A, than CN, which is a strong field ligand. [Fe(OH₂)6]²+ is a positively charged complex whereas [Fe(CN)6]4 is a negatively charged complex. O [Fe(OH₂)6]²+ has fewer paired electrons because the pairing energy is larger than A.。. O [Fe(OH₂)6]²+ is a low spin complex while [Fe(CN)6]4 is a high spin complex.arrow_forward
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